{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 344) - Hexane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Marie C. Haulait-Pirson", "sources": [{"citation": "Leinonen, P. J.; Mackay, D.; Can. J. Chem. Eng. 1973, 51, 230-3.", "pubtype": "paper", "url": "https://doi.org/10.1002/cjce.5450510213"}], "system": "Hexane with Water", "substances": [{"constituent": 1, "name": "Hexane", "formula": "C6H14", "molweight": 86.1754, "casrn": "110-54-3", "inchi": "InChI=1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3", "inchikey": "VLKZOEOYAKHREP-UHFFFAOYSA-N", "sample": "Phillips Petroleum Co.; research grade; purity 99%+; used without further purification."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "doubly distilled."}], "method": "A mixture of (1) and (2) was equilibrated for at least 12 hrs in a 200 mL Teflon stoppered vessel with gentle shaking. The solution was allowed to settle for 6 hrs and the aqueous phase was tested (Tyndall effect). Both phases were analyzed by the gas chromatographic technique of internal standardization. The (1) in the aqueous phase was extracted into 5 mL of heptane and the extract analysed by GLC. The instrument was a Hewlett-Packard model equiped with a flame ionization detector.", "dataset": []}}