{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 385) - Toluene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska", "sources": [{"citation": "Tarassenkow, D. N.; Poloshinzewa, E. N.; Ber. Dtsch. Chem. Ges. 1932, 65B, 184-6.", "pubtype": "paper", "url": "https://doi.org/10.1002/cber.19320650215"}], "system": "Toluene with Water", "substances": [{"constituent": 1, "name": "Toluene", "formula": "C7H8", "molweight": 92.1384, "casrn": "108-88-3", "inchi": "InChI=1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3", "inchikey": "YXFVVABEGXRONW-UHFFFAOYSA-N", "sample": "Kahlbaum, CP; dried ove calcium chloride and distilled from sodium; purity not specified."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Not specified."}], "method": "Alexejew's method was used [1]. No additional details were reported in the paper.", "reference": {"citation": "Alexejew, W.; Ann. Phys. Chem. 28, 305 (1886).", "pubtype": "paper", "url": "https://doi.org/10.1002/andp.18862640611"}, "dataset": [{"series": 1, "title": "Solubility of water in toluene", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "-9e+00", "significand": "-9", "exponent": "0", "sigfigs": "1", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "2e-03", "significand": "2", "exponent": "-3", "sigfigs": "1", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "1e-04", "significand": "1", "exponent": "-4", "sigfigs": "1", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "-3.5e+00", "significand": "-3.5", "exponent": "0", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "5e-03", "significand": "5", "exponent": "-3", "sigfigs": "1", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - 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