{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 259) - Cyclohexane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Marie C. Haulait-Pirson", "sources": [{"citation": "Kirchnerov\u00e1, J.; Cave, G. C. B.; Can. J. Chem. 1976, 54(24), 3909-16.", "pubtype": "paper", "url": "https://doi.org/10.1139/v76-562"}], "system": "Cyclohexane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "distilled and de-ionized"}, {"constituent": 1, "name": "Cyclohexane", "formula": "C6H12", "molweight": 84.1595, "casrn": "110-82-7", "inchi": "InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2", "inchikey": "XDTMQSROBMDMFD-UHFFFAOYSA-N", "sample": "Fisher C-555; purified by double crystallization; purity $\\pu{99.6\\%}$ (gas chromatographic analysis); $d_{4}^{25} = \\pu{0.7734 \\pm 0.00001}$"}], "method": "The Karl Fischer dead-stop back-titration method was used. 50 mL of (1) was placed in the equilibration vessel. A test tube containing 6 mL of (2) was then placed in the vessel so that the rim of the tube rested against the upper inside wall of the vessel. The vessel was then stoppered, placed inside a plastic bag and submerged in a water thermostat. Trials had shown that the concentration of (2) in (1) became constant within two days. 10 mL of (1) saturated with (2) were transferred to the titration vessel for water determination. Apparatus is described in the paper.", "reference": {"citation": "Goldman, S.; Can. J. Chem. 1974, 52, 1668-80.", "pubtype": "paper", "url": "https://doi.org/10.1139/v74-241"}, "dataset": []}}