{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4477/jsonld#"}], "@id": "", "generatedAt": "10-20-26 04:54:05", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4477/jsonld#", "@type": "sdo:scidataFramework", "uid": "72_151", "title": "Solubility data from IUPAC SDS Volume 72 (page 1615) - Nitromethane with 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene and 3,7,7-Trimethylbicyclo[4.1.0] hept-3-ene", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "obo:NCIT_C25206", "qudt:K", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The analytical method was used. Liquid-liquid equilibrium was determined as described in Antosik [1]. The equilibrium cell of about 50 mL capacity, equipped with a magnetic stirrer, was sealed in a water jacket, and circulating water from a thermostat ensured temperature constancy. The three-component mixture was stirred in the equilibrium cell for about 30 min, then the mixture was left for about 1 h for complete phase separation, and samples of about 0.2 mL of each of the two phases were withdrawn from the equilibrium cell through a silicone-rubber septum using a syringe for gas chromatography analyses.", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Antosik, M.; J. Chem. 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Nitromethane with 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene and 3,7,7-Trimethylbicyclo[4.1.0] hept-3-ene", "url": "https://doi.org/10.1063/1.1342856"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}