{"compilation": {"title": "Solubility data from IUPAC SDS Volume 38 (page ?) - p-Xylene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska", "sources": [{"citation": "Kirchnerov\u00e1, J.; Cave, G. C. B.; Can. J. Chem. 1976, 54(24), 3909-16.", "pubtype": "paper", "url": "https://doi.org/10.1139/v76-562"}], "system": "p-Xylene with Water", "substances": [{"constituent": 1, "name": "1,4-Dimethylbenzene", "formula": "C8H10", "molweight": 106.165, "casrn": "106-42-3", "inchi": "InChI=1S/C8H10/c1-7-3-5-8(2)6-4-7/h3-6H,1-2H3", "inchikey": "URLKBWYHVLBVBO-UHFFFAOYSA-N", "sample": "Fisher 277; purified by double crystallization."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "not specified."}], "method": "Approximately 50 mL of (1) was placed in the equilibration vessel. A test tube containing 6 mL of (2) was then placed in the vessel so that the rim of the test tube rested against the upper inside wall of the vessel. The vessel was then stoppered, placed inside a plastic bag, and the jacketed vessel was emersed up to its neck in a water thermostat. Trials had shown that the stoichiometric concentration of (1) in (2) became constant within two days.<br/>The stoichiometric concentration of water was determined by a conventional Karl Fischer dead-stop back-titration.", "dataset": [{"series": 1, "title": "Solubility of water in 7,8-dimethyltetradecane", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "7.7e-03", "significand": "7.7", "exponent": "-3", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "9.67e-04", "significand": "9.67", "exponent": "-4", "sigfigs": "3", "unit": "1"}]}]}]}}