{"compilation": {"title": "Solubility data from IUPAC SDS Volume 38 (page ?) - m-Xylene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Glenn T. Hefter", "sources": [{"citation": "Sanemasa, I.; Araki, M.; Deguchi, T.; Nagai, H.; Bull. Chem. Soc. Jpn. 1982, 55, 1054-62.", "pubtype": "paper", "url": "https://doi.org/10.1246/bcsj.55.1054"}], "system": "m-Xylene with Water", "substances": [{"constituent": 1, "name": "1,3-Dimethylbenzene", "formula": "C8H10", "molweight": 106.165, "casrn": "108-38-3", "inchi": "InChI=1S/C8H10/c1-7-4-3-5-8(2)6-7/h3-6H,1-2H3", "inchikey": "IVSZLXZYQVIEFR-UHFFFAOYSA-N", "sample": "Analytical reagent grade (Wako Pure Chemical Ind. Ltd.), stated purity 98.0%, used without further purification."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Redistilled; no further details given."}], "method": "The apparatus is similar to an earlier design [2] and is described in detail in the paper. 100-200 mL of [2] and 10-20 mL of liquid [1] were placed in separate but connected thermostatted flasks. After thermal equilibrium was established a recirculating stream of air was used to vaporize liquid [1] and to transport the vapor to the flask containing [2]. Five 10 mL aliquots were withdrawn into separatory funnels. The concentration of [1] in [2] was then determined by extraction into chloroform followed by UV-spectrophotometry. Standards for the spectrophotometry were prepared by weight from pure liquid solutes.", "reference": {"citation": "Sanemasa, I.; Araki, M.; Deguchi, T.; Nagai, H.; Chem. Lett. 1981, 225-8.", "pubtype": "paper", "url": "https://doi.org/10.1246/cl.1981.225"}, "dataset": [{"series": 1, "title": "Solubility of m-xylene in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount concentration (1)", "number": "1.49e-03", "significand": "1.49", "exponent": "-3", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "2.68e-05", "significand": "2.68", "exponent": "-5", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.58e-02", "significand": "1.58", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount concentration (1)", "number": "1.52e-03", "significand": "1.52", "exponent": "-3", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "2.75e-05", "significand": "2.75", "exponent": "-5", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.62e-02", "significand": "1.62", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.5e+01", "significand": "3.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount concentration (1)", "number": "1.57e-03", "significand": "1.57", "exponent": "-3", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "2.85e-05", "significand": "2.85", "exponent": "-5", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.68e-02", "significand": "1.68", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "4.5e+01", "significand": "4.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount concentration (1)", "number": "1.73e-03", "significand": "1.73", "exponent": "-3", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "3.15e-05", "significand": "3.15", "exponent": "-5", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.86e-02", "significand": "1.86", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}]}]}}