{"compilation": {"title": "Solubility data from IUPAC SDS Volume 38 (page ?) - Tridecane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Marie C. Haulait-Pirson", "sources": [{"citation": "Schatzberg, P.; J. Phys. Chem. 1963, 67, 776-9.", "pubtype": "paper", "url": "https://doi.org/10.1021/j100798a014"}], "system": "Tridecane with Water", "substances": [{"constituent": 1, "name": "Tridecane", "formula": "C13H28", "molweight": 184.361, "casrn": "629-50-5", "inchi": "InChI=1S/C13H28/c1-3-5-7-9-11-13-12-10-8-6-4-2/h3-13H2,1-2H3", "inchikey": "IIYFAKIEWZDVMP-UHFFFAOYSA-N", "sample": "Phillips Petroleum Co.; research grade; 99.73 mole%; passed repeatedly through a column of silica gel until no absorption occurred in the 220 to 340 nm spectral range."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled and deionized."}], "method": "(1) was saturated by storing over a layer of (2) in a brown glass bottle without any agitation. The bottle was sealed with serum cap and completely submerged in the water-bath for seven days. A 20-mL sample was withdrawn with a silicone-hydrophobized hypodermic syringe. Stabilized Karl Fischer reagent diluted to a titer of 1.0-1.3 mg (2)/mL was used to titrate (2) in (1) directly in the presence of methanol to a 'dead-stop' end-point using a Beckman KF3 automatic titrimeter.", "dataset": [{"series": 1, "title": "Solubility of water in tridecane", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "6.1e-04", "significand": "6.1", "exponent": "-4", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (2)", "number": "6e+01", "significand": "6", "exponent": "1", "sigfigs": "1", "unit": "mg/kg"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "4.0e+01", "significand": "4.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "1.26e-03", "significand": "1.26", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (2)", "number": "1.23e+02", "significand": "1.23", "exponent": "2", "sigfigs": "3", "unit": "mg/kg"}], "supplemental": []}]}]}}