{"compilation": {"title": "Solubility data from IUPAC SDS Volume 38 (page ?) - m-Xylene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska", "sources": [{"citation": "Chernoglazova, F. S.; Simulin, Yu. N.; Zh. Fiz. Khim. 1976, 50, 809.", "pubtype": "paper"}], "system": "m-Xylene with Water", "substances": [{"constituent": 1, "name": "1,3-Dimethylbenzene", "formula": "C8H10", "molweight": 106.165, "casrn": "108-38-3", "inchi": "InChI=1S/C8H10/c1-7-4-3-5-8(2)6-7/h3-6H,1-2H3", "inchikey": "IVSZLXZYQVIEFR-UHFFFAOYSA-N", "sample": "Source not specified; 99.9 purity by glc."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled."}], "method": "The solubility of (1) in (2) was determined by the synthetic method of Fuhner [1]. Glass tubes filled with 50-100 mL of (2) were frozen and then (1) was micropipetted. Next, the tubes were sealed and thermostatted for 6 hrs at 70 \u00b0C and 72 hrs at 20 \u00b0C. The solubility was followed visually. The samples were incremented at regular steps 0.005 g (1)/100 g (2). The mean value from 5-6 determinations was adopted. The solubility of (2) in (1) was determined by gas chromatography. The LKhM-7a instrument equipped with a katharometer was employed.", "reference": {"citation": "F\u00fchner, H.; Ber. Dtsch. Chem. Ges. 1924, 57, 510-15.", "pubtype": "paper", "url": "https://doi.org/10.1002/cber.19240570326"}, "dataset": [{"series": 2, "title": "Solubility of Water in m_Xylene", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "3.4e-02", "significand": "3.4", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "2.0e-03", "significand": "2.0", "exponent": "-3", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (2)", "number": "3.4e-02", "significand": "3.4", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "4.0e+01", "significand": "4.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "6.7e-02", "significand": "6.7", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "3.9e-03", "significand": "3.9", "exponent": "-3", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (2)", "number": "6.7e-02", "significand": "6.7", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "7.0e+01", "significand": "7.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "1.90e-01", "significand": "1.90", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "1.11e-02", "significand": "1.11", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (2)", "number": "1.90e-01", "significand": "1.90", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>2</sub>/100 g sln"}]}]}, {"series": 1, "title": "Solubility of m-xylene in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "1.6e-02", "significand": "1.6", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "2.7e-05", "significand": "2.7", "exponent": "-5", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "4.0e+01", "significand": "4.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "2.2e-02", "significand": "2.2", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "3.7e-05", "significand": "3.7", "exponent": "-5", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "7.0e+01", "significand": "7.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "3.8e-02", "significand": "3.8", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "6.4e-05", "significand": "6.4", "exponent": "-5", "sigfigs": "2", "unit": "1"}]}]}]}}