{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/2568/jsonld#"}], "@id": "", "generatedAt": "08-20-26 19:49:14", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/2568/jsonld#", "@type": "sdo:scidataFramework", "uid": "60_96", "title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tetrachloromethane with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Ari L. Horvath", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:DEG_C", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The multiple equilibrium technique was used to measure the Henry's law constant (H) as described by McAuliffe [1]. A known volume of seawater in a syringe was shaken with a known volume of tetrachloromethane. After equilibration, the headspace was separated and analyzed for tetrachloromethane. A gas chromatograph with an electron capture detector was used for the analysis.", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "McAuliffe, C. D.; Chem. Techn. 1971, 1, 46."}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Tetrachloromethane", "formula": "CCl4", "casrn": "56-23-5", "iupacname": "tetrachloromethane", "inchikey": "VZGDMQKNWNREIO-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Tetrachloromethane", "description": "Source and purity not given.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "Samples from 48° N to 65° S in the Atlantic in late 1981.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Tetrachloromethane with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "text": null}, {"@id": "condition/2/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "1.0e+01", "significand": 1.0, "exponent": 1, "sigfigs": 2}, {"@id": "condition/3/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "1.5e+01", "significand": 1.5, "exponent": 1, "sigfigs": 2}, {"@id": "condition/4/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.0e+01", "significand": 2.0, "exponent": 1, "sigfigs": 2}, {"@id": "condition/5/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.5e+01", "significand": 2.5, "exponent": 1, "sigfigs": 2}, {"@id": "condition/6/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.3e+01", "significand": 3.3, "exponent": 1, "sigfigs": 2}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "60:096:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.596e-02", "significand": 5.596, "exponent": -2, "sigfigs": 4}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.557e-05", "significand": 6.557, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Henry's Law Solubility Coefficient", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.100e-01", "significand": 7.1, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "60:096:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.759e-02", "significand": 5.759, "exponent": -2, "sigfigs": 4}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.748e-05", "significand": 6.748, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Henry's Law Solubility Coefficient", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.716e-01", "significand": 8.716, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "60:096:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.911e-02", "significand": 5.911, "exponent": -2, "sigfigs": 4}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.927e-05", "significand": 6.927, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Henry's Law Solubility Coefficient", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.0624e+00", "significand": 1.0624, "exponent": 0, "sigfigs": 5}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "60:096:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.049e-02", "significand": 6.049, "exponent": -2, "sigfigs": 4}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.088e-05", "significand": 7.088, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Henry's Law Solubility Coefficient", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.2863e+00", "significand": 1.2863, "exponent": 0, "sigfigs": 5}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "60:096:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.180e-02", "significand": 6.18, "exponent": -2, "sigfigs": 4}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.242e-05", "significand": 7.242, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Henry's Law Solubility Coefficient", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.5473e+00", "significand": 1.5473, "exponent": 0, "sigfigs": 5}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "60:096:001:001:006", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.625e-02", "significand": 6.625, "exponent": -2, "sigfigs": 4}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.763e-05", "significand": 7.763, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Henry's Law Solubility Coefficient", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.0536e+00", "significand": 2.0536, "exponent": 0, "sigfigs": 5}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Hunter-Smith, R. J.; Balls, P. W.; Liss, P. S.; Tellus 35B, 170 (1983).", "doi": "10.1111/j.1600-0889.1983.tb00021.x", "url": "https://doi.org/10.1111/j.1600-0889.1983.tb00021.x"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tetrachloromethane with Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-60.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}