{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/850/jsonld#"}], "@id": "", "generatedAt": "08-19-26 18:25:29", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/850/jsonld#", "@type": "sdo:scidataFramework", "uid": "38_288", "title": "Solubility data from IUPAC SDS Volume 38 (page ?) - Biphenyl with Sodium chloride and Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "M. Kleinschmidt", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "W.Y. Shiu", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["Equilibration flask: 50-mL glass-stoppered flask. The flask was heated in a hot-water bath until the hydrocarbon was melted, then shaken vigorously while cooling until excess hydrocarbon had recrystallized. The flask was then placed into a water bath thermostatically controlled at 25.00 \u00b1 0.05 \u00b0C for at least 48 hr, and shaken occasionally during that time. Samples were withdrawn with a 10-mL transfer pipet, diluted appropriately and analyzed using a spectrophotometer in the ultra-violet region of the spectrum.", "afq:AFQ_0000168", "afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:DEG_C", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "Equilibration flask: 50-mL glass-stoppered flask. The flask was heated in a hot-water bath until the hydrocarbon was melted, then shaken vigorously while cooling until excess hydrocarbon had recrystallized. The flask was then placed into a water bath thermostatically controlled at 25.00 \u00b1 0.05 \u00b0C for at least 48 hr, and shaken occasionally during that time. Samples were withdrawn with a 10-mL transfer pipet, diluted appropriately and analyzed using a spectrophotometer in the ultra-violet region of the spectrum.", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Weast, R. C.; CRC Handbook of Chemistry and Physics, 59th Edition; CRC Press, 1978, pp D299-D300."}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Biphenyl", "formula": "C12H10", "casrn": "92-52-4", "iupacname": "1,1'-biphenyl", "inchikey": "ZUOUZKKEUPVFJK-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Sodium chloride", "formula": "NaCl", "casrn": "7647-14-5", "iupacname": "sodium chloride", "inchikey": "FAPWRFPIFSIZLT-UHFFFAOYSA-M"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Biphenyl", "description": "recrystallized from methanol (source not specified)", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Sodium chloride", "description": "reagent grade, dried at 120°C before weighing (source not specified)", "substance#": "substance/2/"}, {"@id": "chemical/3/", "@type": "sdo:chemical", "name": "Water", "description": "redistilled. (source not specified)", "substance#": "substance/3/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Biphenyl with Sodium chloride and Water", "type": "ternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.5e+01", "significand": 2.5, "exponent": 1, "sigfigs": 2}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/", "datapoint/7/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "38:288:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.16e-07", "significand": 7.16, "exponent": -7, "sigfigs": 3}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.08e-04", "significand": 6.08, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Relative mass - solution (2)", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.325e+01", "significand": 1.325, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/1/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/1/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.98e-05", "significand": 3.98, "exponent": -5, "sigfigs": 3}}, {"@id": "datapoint/1/datum/5/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/1/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.29e-01", "significand": 2.29, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "38:288:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.49e-07", "significand": 6.49, "exponent": -7, "sigfigs": 3}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.46e-04", "significand": 5.46, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Relative mass - solution (2)", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.624e+01", "significand": 2.624, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/2/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/2/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.61e-05", "significand": 3.61, "exponent": -5, "sigfigs": 3}}, {"@id": "datapoint/2/datum/5/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/2/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.58e-01", "significand": 4.58, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "38:288:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.55e-07", "significand": 5.55, "exponent": -7, "sigfigs": 3}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.62e-04", "significand": 4.62, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Relative mass - solution (2)", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.905e+01", "significand": 3.905, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/3/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/3/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.08e-05", "significand": 3.08, "exponent": -5, "sigfigs": 3}}, {"@id": "datapoint/3/datum/5/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/3/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.87e-01", "significand": 6.87, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "38:288:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.02e-07", "significand": 5.02, "exponent": -7, "sigfigs": 3}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.16e-04", "significand": 4.16, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Relative mass - solution (2)", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.628e+01", "significand": 4.628, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/4/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/4/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.79e-05", "significand": 2.79, "exponent": -5, "sigfigs": 3}}, {"@id": "datapoint/4/datum/5/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/4/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.18e-01", "significand": 8.18, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "38:288:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.01e-07", "significand": 5.01, "exponent": -7, "sigfigs": 3}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.13e-04", "significand": 4.13, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Relative mass - solution (2)", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.162e+01", "significand": 5.162, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/5/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/5/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.78e-05", "significand": 2.78, "exponent": -5, "sigfigs": 3}}, {"@id": "datapoint/5/datum/5/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/5/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.16e-01", "significand": 9.16, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "38:288:001:001:006", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.32e-07", "significand": 4.32, "exponent": -7, "sigfigs": 3}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.54e-04", "significand": 3.54, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Relative mass - solution (2)", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.397e+01", "significand": 6.397, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/6/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/6/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.40e-05", "significand": 2.4, "exponent": -5, "sigfigs": 3}}, {"@id": "datapoint/6/datum/5/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/6/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.145e+00", "significand": 1.145, "exponent": 0, "sigfigs": 4}}]}, {"@id": "datapoint/7/", "@type": "sdo:datapoint", "uid": "38:288:001:001:007", "conditions#": ["condition/7/"], "data": [{"@id": "datapoint/7/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/7/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.21e-07", "significand": 4.21, "exponent": -7, "sigfigs": 3}}, {"@id": "datapoint/7/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/7/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.45e-04", "significand": 3.45, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/7/datum/3/", "@type": "sdo:datum", "quantity": "Relative mass - solution (2)", "value": {"@id": "datapoint/7/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.397e+01", "significand": 6.397, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/7/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/7/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.34e-05", "significand": 2.34, "exponent": -5, "sigfigs": 3}}, {"@id": "datapoint/7/datum/5/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/7/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.145e+00", "significand": 1.145, "exponent": 0, "sigfigs": 4}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Paul, M. A.; J. Am. Chem. Soc. 1952, 74, 5274-7.", "doi": "10.1021/ja01141a011", "url": "https://doi.org/10.1021/ja01141a011"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 38 (page ?) - Biphenyl with Sodium chloride and Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-38.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}