{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/844/jsonld#"}], "@id": "", "generatedAt": "10-19-26 09:48:54", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/844/jsonld#", "@type": "sdo:scidataFramework", "uid": "38_282", "title": "Solubility data from IUPAC SDS Volume 38 (page ?) - Biphenyl with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Glenn T. Hefter", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["Solubilities were determined spectroscopically. Saturated solutions were prepared in two ways: (a) direct mixing of benzene and water for ca. 48 h, (b) dissolution of benzene through the vapor phase. Absorbances of the solutions and their vapors were measured directly at $\\lambda_{\\rm{max}}$ with a Model 450 Perkin-Elmer spectrophotometer with a thermostatted cell holder. Establishment of equilibrium was checked by use of special three compartment cell, details of which are given in the paper.", "afrl:0000269", "afrl:0000270", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "Solubilities were determined spectroscopically. Saturated solutions were prepared in two ways: (a) direct mixing of benzene and water for ca. 48 h, (b) dissolution of benzene through the vapor phase. Absorbances of the solutions and their vapors were measured directly at $\\lambda_{\\rm{max}}$ with a Model 450 Perkin-Elmer spectrophotometer with a thermostatted cell holder. Establishment of equilibrium was checked by use of special three compartment cell, details of which are given in the paper.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Biphenyl", "formula": "C12H10", "casrn": "92-52-4", "iupacname": "1,1'-biphenyl", "inchikey": "ZUOUZKKEUPVFJK-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Biphenyl", "description": "Fluka; puriss, 99.94%, used as received.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "Distilled water, further distilled from alk. $\\ce{KMnO4}$ and acid $\\ce{K2Cr2O7}$; $\\kappa = \\pu{0.8E-6 S cm-1}$.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Biphenyl with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Ben-Naim, A.; Wilf, J.; Yaacobi, M.; J. Phys. Chem. 1973, 77, 95-102.", "doi": "10.1021/j100620a021", "url": "https://doi.org/10.1021/j100620a021"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 38 (page ?) - Biphenyl with Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-38.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}