{"compilation": {"title": "Solubility data from IUPAC SDS Volume 38 (page ?) - d-Limonene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska", "sources": [{"citation": "Massaldi, H. A.; King, C. J.; J. Chem. Eng. Data 1973, 18, 393-7.", "pubtype": "paper", "url": "https://doi.org/10.1021/je60059a024"}], "system": "d-Limonene with Water", "substances": [{"constituent": 1, "name": "d-Limonene", "formula": "C10H16", "molweight": 136.234, "casrn": "5989-27-5", "inchi": "InChI=1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1", "inchikey": "XMGQYMWWDOXHJM-JTQLQIEISA-N", "sample": "Matheson Coleman and bell Co., highest purity; kept under $\\ce{N2}$ atmosphere at -2&deg;C in a dark container; used as received."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Not specified."}], "method": "A technique based on head-space analysis by gas-liquid chromatography was developed to determine solubilities of sparing soluble organics. Saturated solutions need not be prepared in advance whereby phase separation problems are avoided, nor have liquid samples to be analyzed. This method is versatile enough to allow determinations provided that the pure vapor pressure of the substances is known. The gas chromatograph was a Varian Aerograph Model 1740 with a flame ionization detector.", "dataset": [{"series": 1, "title": "Solubility of d-limonene in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "0e+00", "significand": "0", "exponent": "0", "sigfigs": "0", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.3e-06", "significand": "1.3", "exponent": "-6", "sigfigs": "2", "unit": "1"}, {"property": "Solubility (v/v) (2 in 1)", "number": "9.7e+00", "significand": "9.7", "exponent": "0", "sigfigs": "2", "unit": "1"}, {"property": "Amount concentration (1)", "number": "7.08e-05", "significand": "7.08", "exponent": "-5", "sigfigs": "3", "unit": "mol/L"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "9.7e-04", "significand": "9.7", "exponent": "-4", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "5e+00", "significand": "5", "exponent": "0", "sigfigs": "1", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.4e-06", "significand": "1.4", "exponent": "-6", "sigfigs": "2", "unit": "1"}, {"property": "Solubility (v/v) (2 in 1)", "number": "1.04e+01", "significand": "1.04", "exponent": "1", "sigfigs": "3", "unit": "1"}, {"property": "Amount concentration (1)", "number": "7.67e-05", "significand": "7.67", "exponent": "-5", "sigfigs": "3", "unit": "mol/L"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "1.04e-03", "significand": "1.04", "exponent": "-3", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.8e-06", "significand": "1.8", "exponent": "-6", "sigfigs": "2", "unit": "1"}, {"property": "Solubility (v/v) (2 in 1)", "number": "1.38e+01", "significand": "1.38", "exponent": "1", "sigfigs": "3", "unit": "1"}, {"property": "Amount concentration (1)", "number": "1.013e-04", "significand": "1.013", "exponent": "-4", "sigfigs": "4", "unit": "mol/L"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "1.38e-03", "significand": "1.38", "exponent": "-3", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}]}]}}