{"compilation": {"title": "Solubility data from IUPAC SDS Volume 58 (page 175) - Biphenyl with Benzene", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "William E. Acree, Jr.", "sources": [{"citation": "McLaughlin, E.; Zainal, H. A.; J. Chem. Soc. 1959, 863-867.", "pubtype": "paper", "url": "https://doi.org/10.1039/jr9590000863"}], "system": "Biphenyl with Benzene", "substances": [{"constituent": 1, "name": "Biphenyl", "formula": "C12H10", "molweight": 154.208, "casrn": "92-52-4", "inchi": "InChI=1S/C12H10/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H", "inchikey": "ZUOUZKKEUPVFJK-UHFFFAOYSA-N", "sample": "Purity not specified, Gesselschaft fur Teerverwertung, passed over an alumina column with benzene eluant."}, {"constituent": 2, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "“AnalaR”, was dried over sodium wire and freshly distilled before use."}], "method": "Constant temperature bath and a precision thermometer. Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by noting the temperature at which the last trace of solid solute disappeared.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.102e+02", "significand": "3.102", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.118e-01", "significand": "5.118", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.882e-01", "significand": "4.882", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.208e+02", "significand": "3.208", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.478e-01", "significand": "6.478", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "3.522e-01", "significand": "3.522", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.324e+02", "significand": "3.324", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.195e-01", "significand": "8.195", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "1.805e-01", "significand": "1.805", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.364e+02", "significand": "3.364", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.916e-01", "significand": "8.916", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "1.084e-01", "significand": "1.084", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": []}]}]}}