{"compilation": {"title": "Solubility data from IUPAC SDS Volume 78 (page ?) - Acetonitrile with 2-Alcohols", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 9, 134-144 (1965).", "pubtype": "paper", "url": "https://doi.org/10.1016/0026-265x(65)90094-9"}], "system": "Acetonitrile with 2-Alcohols", "substances": [{"constituent": 1, "name": "Acetonitrile", "formula": "C2H3N", "molweight": 41.052, "casrn": "75-05-8", "inchi": "InChI=1S/C2H3N/c1-2-3/h1H3", "inchikey": "WEVYAHXRMPXWCK-UHFFFAOYSA-N", "sample": "Baker Chemical Co.; reagent No. 9011; $n_{D}^{20}$ = 1.3445, $d_{4}^{20}$ = 0.780."}, {"constituent": 2, "name": "2-Alcohols (C11-C19)", "formula": "C11H24O - C19H40O", "molweight": 0.0, "sample": "Some alcohols obtained from Aldrich Chemical Co.; all other alcohols prepared by reduction of the corresponding methyl ketones with lithium aluminum hydride; purified by gas-liquid partition chromatography."}], "method": "The synthetic method was used. A Reichert microscope, type RCH, equipped with a heating stage was used as described elsewhere [1]. The disappearance and reappearance of the interface between (1) and (2) could be observed without difficulty.", "reference": {"citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).", "pubtype": "paper", "url": "https://doi.org/10.1007/bf02635572"}, "dataset": [{"series": 1, "title": "Upper critical solution temperatures of the systems acetonitrile (1) + 2-alcohol (2)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.25e+01", "significand": "2.25", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.957e+02", "significand": "2.957", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.90e+01", "significand": "2.90", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.022e+02", "significand": "3.022", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.50e+01", "significand": "3.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.082e+02", "significand": "3.082", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.95e+01", "significand": "3.95", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.127e+02", "significand": "3.127", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "4.50e+01", "significand": "4.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.182e+02", "significand": "3.182", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "5.00e+01", "significand": "5.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.232e+02", "significand": "3.232", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "5.55e+01", "significand": "5.55", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.287e+02", "significand": "3.287", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "6.60e+01", "significand": "6.60", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.392e+02", "significand": "3.392", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}]}]}}