{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 208) - Fluorobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Jockers, R.; Ph.D. Dissertation, University of Bochum, Bochum, 1976.", "pubtype": "dissertation"}], "system": "Fluorobenzene with Water", "substances": [{"constituent": 1, "name": "Fluorobenzene", "formula": "C6H5F", "molweight": 96.1023, "casrn": "462-06-6", "inchi": "InChI=1S/C6H5F/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "PYLWMHQQBFSUBP-UHFFFAOYSA-N", "sample": "Fluka AG., Buchs, Schweiz, 99.5% pure, redistilled before use."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Boiled with $\\ce{KMnO4}$ and redistilled before use."}], "method": "The measurements were made using a high temperature, high pressure optical cell made from stainless steel with an internal stirrer. Predetermined mixtures of fluorobenzene in water were introduced into the cell and homogenized at various temperatures and pressures. The phase transitions were observed through a sapphire window at the appropriate temperatures and pressures. Further details have been included in [1,2].", "reference": {"citation": "Jockers, R.; Schneider, G. M.; Ber. Bunsenges. Phys. Chem. 1978, 83, 576-82.", "pubtype": "paper", "url": "https://doi.org/10.1002/bbpc.197800121"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.840e+02", "significand": "2.840", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient pressure", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.533e-01", "significand": "1.533", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "4.9130e+02", "significand": "4.9130", "exponent": "2", "sigfigs": "5", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "5.1123e+00", "significand": "5.1123", "exponent": "0", "sigfigs": "5", "unit": "mol/kg"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.895e+02", "significand": "2.895", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient pressure", "number": "1.14e+02", "significand": "1.14", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.970e-01", "significand": "1.970", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "5.6684e+02", "significand": "5.6684", "exponent": "2", "sigfigs": "5", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "5.8985e+00", "significand": "5.8985", "exponent": "0", "sigfigs": "5", "unit": "mol/kg"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.790e+02", "significand": "2.790", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient pressure", "number": "1.03e+02", "significand": "1.03", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.970e-01", "significand": "1.970", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "5.6684e+02", "significand": "5.6684", "exponent": "2", "sigfigs": "5", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "5.8985e+00", "significand": "5.8985", "exponent": "0", "sigfigs": "5", "unit": "mol/kg"}], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.735e+02", "significand": "2.735", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient pressure", "number": "9.6e+01", "significand": "9.6", "exponent": "1", "sigfigs": "2", "unit": "$\\pu{bar}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.970e-01", "significand": "1.970", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "5.6684e+02", "significand": "5.6684", "exponent": "2", "sigfigs": "5", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "5.8985e+00", "significand": "5.8985", "exponent": "0", "sigfigs": "5", "unit": "mol/kg"}], "supplemental": []}]}]}}