{"compilation": {"title": "Solubility data from IUPAC SDS Volume 78 (page ?) - Acetonitrile with Esters (C24 - C32)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 9, 134-144 (1965).", "pubtype": "paper", "url": "https://doi.org/10.1016/0026-265x(65)90094-9"}], "system": "Acetonitrile with Esters (C24 - C32)", "substances": [{"constituent": 1, "name": "Acetonitrile", "formula": "C2H3N", "molweight": 41.052, "casrn": "75-05-8", "inchi": "InChI=1S/C2H3N/c1-2-3/h1H3", "inchikey": "WEVYAHXRMPXWCK-UHFFFAOYSA-N", "sample": "Baker Chemical Co.; reagent No. 9011; $n_{D}^{20}$ = 1.3445, $d_{4}^{20}$ = 0.780."}, {"constituent": 2, "name": "Esters (C24 - C32)", "formula": "C24H48O2 - C32H64O2", "molweight": 0.0, "sample": "Synthesized by transesterification of methyl esters and acetates using sodium methanoate as catalyst; purified by gas-liquid partition and thin-layer adsorption chromatography."}], "method": "The synthetic method was used. A Reichert microscope, type RCH, equipped with a heating stage was used as described elsewhere [1]. The disappearance and reappearance of the interface between (1) and (2) could be observed without difficulty.", "reference": {"citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).", "pubtype": "paper", "url": "https://doi.org/10.1007/bf02635572"}, "dataset": [{"series": 1, "title": "Upper critical solution temperatures of the binary systems acetonitrile (1) + ester (2)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.040e+02", "significand": "1.040", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.772e+02", "significand": "3.772", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "1.045e+02", "significand": "1.045", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.777e+02", "significand": "3.777", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "1.180e+02", "significand": "1.180", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.912e+02", "significand": "3.912", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "1.180e+02", "significand": "1.180", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.912e+02", "significand": "3.912", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "1.300e+02", "significand": "1.300", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "4.032e+02", "significand": "4.032", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "1.300e+02", "significand": "1.300", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "4.032e+02", "significand": "4.032", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "1.405e+02", "significand": "1.405", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "4.137e+02", "significand": "4.137", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "1.405e+02", "significand": "1.405", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "4.137e+02", "significand": "4.137", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 9, "conditions": [{"property": "Ambient temperature", "number": "1.505e+02", "significand": "1.505", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "4.237e+02", "significand": "4.237", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}]}]}}