{"compilation": {"title": "Solubility data from IUPAC SDS Volume 78 (page ?) - Acetonitrile with Ethyl octadecanoate", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Sedgwick, R. S.; Hoerr, C. W.; Harwood, H. J.; J. Org. Chem. 17, 327 (1952).", "pubtype": "paper", "url": "https://doi.org/10.1021/jo01136a023"}], "system": "Acetonitrile with Ethyl octadecanoate", "substances": [{"constituent": 1, "name": "Acetonitrile", "formula": "C2H3N", "molweight": 41.052, "casrn": "75-05-8", "inchi": "InChI=1S/C2H3N/c1-2-3/h1H3", "inchikey": "WEVYAHXRMPXWCK-UHFFFAOYSA-N", "sample": "Source not specified; best grade; freshly distilled."}, {"constituent": 2, "name": "Ethyl octadecanoate", "formula": "C20H40O2", "molweight": 312.53, "casrn": "111-61-5", "inchi": "InChI=1S/C20H40O2/c1-3-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20(21)22-4-2/h3-19H2,1-2H3", "inchikey": "MVLVMROFTAUDAG-UHFFFAOYSA-N", "sample": "Prepared by direct esterification of highly purified fatty acid with the appropriate alcohol; fractionated under a vacuum in a Stedman-packed column; FP = 31.36&deg;C."}], "method": "The synthetic method was used. The solubilities were determined by observing visually the temperature at which crystals appear upon cooling and dissolve upon heating solutions containing known concentrations of solutes. The procedure and equipment were described elsewhere [1].", "reference": {"citation": "Hoerr, C. W.; Binkerd, E. F.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 9, 68-80 (1944).", "pubtype": "paper", "url": "https://doi.org/10.1021/jo01183a008"}, "dataset": [{"series": 1, "title": "Solubility of ethyl octadecanoate (2) in acetonitrile (1)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.00e+01", "significand": "1.00", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}, {"property": "Ambient temperature", "number": "2.832e+02", "significand": "2.832", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Relative mass - solution (2)", "number": "2e-01", "significand": "2", "exponent": "-1", "sigfigs": "1", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Percent mass fraction (2)", "number": "2e-03", "significand": "2", "exponent": "-3", "sigfigs": "1", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "3e-04", "significand": "3", "exponent": "-4", "sigfigs": "1", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.00e+01", "significand": "2.00", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Relative mass - solution (2)", "number": "1.5e+00", "significand": "1.5", "exponent": "0", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Percent mass fraction (2)", "number": "1.5e-02", "significand": "1.5", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2e-03", "significand": "2", "exponent": "-3", "sigfigs": "1", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.00e+01", "significand": "3.00", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}, {"property": "Ambient temperature", "number": "3.032e+02", "significand": "3.032", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Relative mass - solution (2)", "number": "7.2e+00", "significand": "7.2", "exponent": "0", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Percent mass fraction (2)", "number": "6.7e-02", "significand": "6.7", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "9e-03", "significand": "9", "exponent": "-3", "sigfigs": "1", "unit": "1"}]}]}]}}