{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 139) - Bromobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Hutchinson, C. A.; Lyon, A. M.; Columbia University Report A-745, July 1, 1943.", "pubtype": "report"}], "system": "Bromobenzene with Water", "substances": [{"constituent": 1, "name": "Bromobenzene", "formula": "C6H5Br", "molweight": 157.008, "casrn": "108-86-1", "inchi": "InChI=1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "QARVLSVVCXYDNA-UHFFFAOYSA-N", "sample": "Distilled."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source is not known, purified and dried before use."}], "method": "A mixture of 1 to 15 volume ratio of solute to solvent was placed in an equilibration flask and then lowered into a thermostat water bath. The assembly was shaken mechanically for about 90 min. at constant temperature. The amount of water in the organic phase was determined by a modified Karl Fisher titration. The determination was done in triplicate. The description of the procedure was taken from a secondary source [1]. The original report is no longer available.", "reference": {"citation": "Eidinoff, M. L. In \"Production of Heavy Water\", National Nuclear Energy Series Division III-Vol. 4F, Murphy, G. M.; Urey, H. C.; Kirshenbaum, I.; Eds.; McGraw-Hill: New York, 1955; Part II, Chapter 7, pp 129-44.", "pubtype": "chapter"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.616e-03", "significand": "2.616", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "3.009e-01", "significand": "3.009", "exponent": "-1", "sigfigs": "4", "unit": "g/kg"}, {"property": "Molality (1)", "number": "1.67e-02", "significand": "1.67", "exponent": "-2", "sigfigs": "3", "unit": "mol/kg"}], "supplemental": []}]}]}}