{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 159) - Chlorobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Bell, R. P.; J. Chem. Soc. 1932, 2905-11.", "pubtype": "paper", "url": "https://doi.org/10.1039/jr9320002905"}], "system": "Chlorobenzene with Water", "substances": [{"constituent": 1, "name": "Chlorobenzene", "formula": "C6H5C1", "molweight": 112.557, "casrn": "108-90-7", "inchi": "InChI=1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "MVPPADPHJFYWMZ-UHFFFAOYSA-N", "sample": "Distilled (compiler)."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Merck reagent, analytical grade, redistilled before use."}], "method": "Mixtures of solute and solvent in about 1 to 5 ratios were rotated in a thermostat bath for 12 hours. After equilibrium was attained, samples were withdrawn and filtered through cotton-wool. The determination of the water content was based upon the reaction of water with o-naphthoxydichlorophosphine. The evolved $\\ce{HCl}$ was absorbed in water and titrated with standard $\\ce{NaOH}$ solution [1]. From 2-4 successive determinations were made with the solvent.", "reference": {"citation": "Bell, R. P.; J. Chem. Soc. 1932, 2903.", "pubtype": "paper", "url": "https://doi.org/10.1039/jr9320002903"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.488e-03", "significand": "1.488", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Amount concentration (1)", "number": "1.471e-02", "significand": "1.471", "exponent": "-2", "sigfigs": "4", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mass concentration (m/v) (1)", "number": "2.64e-01", "significand": "2.64", "exponent": "-1", "sigfigs": "3", "unit": "g/dm<sup>3</sup>"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.719e-03", "significand": "1.719", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Amount concentration (1)", "number": "1.691e-02", "significand": "1.691", "exponent": "-2", "sigfigs": "4", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mass concentration (m/v) (1)", "number": "3.05e-01", "significand": "3.05", "exponent": "-1", "sigfigs": "3", "unit": "g/dm<sup>3</sup>"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.995e-03", "significand": "1.995", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Amount concentration (1)", "number": "1.953e-02", "significand": "1.953", "exponent": "-2", "sigfigs": "4", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mass concentration (m/v) (1)", "number": "3.54e-01", "significand": "3.54", "exponent": "-1", "sigfigs": "3", "unit": "g/dm<sup>3</sup>"}]}]}]}}