{"compilation": {"title": "Solubility data from IUPAC SDS Volume 58 (page 195) - Biphenyl with Carbon disulfide", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "William E. Acree, Jr.", "sources": [{"citation": "Warner, J. C.; Scheib, R. C.; Svirbely, W. J.; J. Chem. Phys. 1934, 2, 590-594.", "pubtype": "paper", "url": "https://doi.org/10.1063/1.1749539"}], "system": "Biphenyl with Carbon disulfide", "substances": [{"constituent": 1, "name": "Biphenyl", "formula": "C12H10", "molweight": 154.208, "casrn": "92-52-4", "inchi": "InChI=1S/C12H10/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H", "inchikey": "ZUOUZKKEUPVFJK-UHFFFAOYSA-N", "sample": "Purity not specified, Eastman Kodak Company, Rochester, New York, USA, was recrystallized several times from alcohol."}, {"constituent": 2, "name": "Carbon disulfide", "formula": "CS2", "molweight": 76.1407, "casrn": "75-15-0", "inchi": "InChI=1S/CS2/c2-1-3", "inchikey": "QGJOPFRUJISHPQ-UHFFFAOYSA-N", "sample": "Purity not given, Eastman Kodak Company, was dried over calcium chloride and distilled twice from mercury."}], "method": "Constant temperature bath and a precision thermometer. Mixtures of known concentrations sealed in glass tubes and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by noting the temperature at which the last trace of solid solute disappeared. Measurements repeated several times to verify results.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.016e+02", "significand": "3.016", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.04e-01", "significand": "4.04", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "5.96e-01", "significand": "5.96", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.098e+02", "significand": "3.098", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.98e-01", "significand": "4.98", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "5.02e-01", "significand": "5.02", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.109e+02", "significand": "3.109", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.14e-01", "significand": "5.14", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.86e-01", "significand": "4.86", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.114e+02", "significand": "3.114", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.20e-01", "significand": "5.20", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.80e-01", "significand": "4.80", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.139e+02", "significand": "3.139", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.53e-01", "significand": "5.53", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.47e-01", "significand": "4.47", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "3.173e+02", "significand": "3.173", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.95e-01", "significand": "5.95", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.05e-01", "significand": "4.05", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "3.208e+02", "significand": "3.208", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.37e-01", "significand": "6.37", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "3.63e-01", "significand": "3.63", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "3.227e+02", "significand": "3.227", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.74e-01", "significand": "6.74", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "3.26e-01", "significand": "3.26", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 9, "conditions": [{"property": "Ambient temperature", "number": "3.245e+02", "significand": "3.245", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.94e-01", "significand": "6.94", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "3.06e-01", "significand": "3.06", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 10, "conditions": [{"property": "Ambient temperature", "number": "3.315e+02", "significand": "3.315", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.10e-01", "significand": "8.10", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "1.90e-01", "significand": "1.90", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}]}]}}