{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide with Polyimide Upilex R", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Yuri P. Yampol'skii", "sources": [{"citation": "Sada, E.; Kumazawa, H.; Xu, P.; J. Appl. Polym. Sci. 35, 1497 (1988).", "pubtype": "paper", "url": "https://doi.org/10.1002/app.1988.070350608"}], "system": "Carbon dioxide with Polyimide Upilex R", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "Polyimide Upilex R: Ube Industries; $T_{\\rm{g}}$ = 558 K."}, {"constituent": 2, "name": "Polyimide of BPDA and ODA", "formula": null, "molweight": 0.0, "casrn": "26615-45-2"}], "method": "Sorption was measured by pressure decay method. The apparatus was similar to that described in [1].", "reference": {"citation": "Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687.", "pubtype": "paper", "url": "https://doi.org/10.1002/pol.1976.180140410"}, "dataset": [{"series": 2, "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Fugacity", "number": "-1.59e+01", "significand": "-1.59", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Fugacity", "number": "-2.90e+01", "significand": "-2.90", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": []}]}, {"series": 1, "title": "Dual sorption parameters for carbon dioxide in Upilex polymide", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.03e+02", "significand": "3.03", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "1.24e+00", "significand": "1.24", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "7.39e+00", "significand": "7.39", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.70e+00", "significand": "1.70", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.13e+02", "significand": "3.13", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "1.04e+00", "significand": "1.04", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "5.67e+00", "significand": "5.67", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.23e+00", "significand": "1.23", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.23e+02", "significand": "3.23", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "8.17e-01", "significand": "8.17", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "4.27e+00", "significand": "4.27", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "8.65e-01", "significand": "8.65", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.33e+02", "significand": "3.33", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.92e-01", "significand": "6.92", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "3.34e+00", "significand": "3.34", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "6.35e-01", "significand": "6.35", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.03e+02", "significand": "3.03", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "1.35e+00", "significand": "1.35", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "6.93e+00", "significand": "6.93", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.91e+00", "significand": "1.91", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "3.13e+02", "significand": "3.13", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "1.12e+00", "significand": "1.12", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "5.28e+00", "significand": "5.28", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.35e+00", "significand": "1.35", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "3.23e+02", "significand": "3.23", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "8.75e-01", "significand": "8.75", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "3.95e+00", "significand": "3.95", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "9.54e-01", "significand": "9.54", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "3.33e+02", "significand": "3.33", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "7.36e-01", "significand": "7.36", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "3.09e+00", "significand": "3.09", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "6.83e-01", "significand": "6.83", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}]}]}}