{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4016/jsonld#"}], "@id": "", "generatedAt": "10-17-26 14:22:29", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4016/jsonld#", "@type": "sdo:scidataFramework", "uid": "70_190", "title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide with Polyimide Kapton H", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Yuri P. Yampol'skii", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000270", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "A method based on the principle of material balance for all gas introduced into the cell was employed [1,2].", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Sanders, E. S.; Ph.D. Dissertation, North Carolina State University, Raleigh, NC, 1983."}, {"@id": "procedure/1/reference/2/", "@type": "sdo:reference", "number": 2, "citation": "Koros, W. J.; Paul, D. R.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 1903.", "doi": "10.1002/pol.1976.180141014", "url": "https://doi.org/10.1002/pol.1976.180141014"}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Carbon dioxide", "formula": "CO2", "casrn": "124-38-9", "iupacname": "carbon dioxide", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Copoly(pyromellitic dianhydride-oxydianiline) (PMDA-ODA)", "formula": null, "casrn": "25036-53-7"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Carbon dioxide", "description": "Matheson Gas precision mixture $\\pu{50 \\pm 0.5\\%}$ each $\\ce{CO2}/\\ce{CH4}$.<br/>Composition verified by GC against a certified Matheson gas reference.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Copoly(pyromellitic dianhydride-oxydianiline) (PMDA-ODA)", "description": "Commercial Kapton H: $d = \\pu{1.430 g mL-1}$, $M_{\\rm{w}} = \\pu{39200}$.<br/>PMDA-ODA: $d = \\pu{1.402 g mL-1}$, $M_{\\rm{w}} = \\pu{36900}$; structure confirmed by IR.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Carbon dioxide with Polyimide Kapton H", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solute", "role#": "afrl:0000270"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "O'Brien, K. C.; Koros, W. J.; Husk, G. R.; Polym. Eng. Sci. 27, 211 (1987).", "doi": "10.1002/pen.760270306", "url": "https://doi.org/10.1002/pen.760270306"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide with Polyimide Kapton H", "url": "https://doi.org/10.1063/1.556050"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}