{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide with Tetramethylpolycarbonate (TMPC)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Yuri P. Yampol'skii", "sources": [{"citation": "Fleming, G. K.; Koros, W. J.; J. Polym. Sci. B: Polym. Phys. 28, 1137 (1990).", "pubtype": "paper", "url": "https://doi.org/10.1002/polb.1990.090280711"}], "system": "Carbon dioxide with Tetramethylpolycarbonate (TMPC)", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "$\\ce{CO2}$: Linde Inc., purity 99.99%. TMPC: Bayer AG, $\\rho = \\pu{1.083 g mL-1}$, $T_{\\rm{g}}$ = 475 K, $d$ spacing 6.0 \u212b (WAXD)."}, {"constituent": 2, "name": "Tetramethylpolycarbonate (TMPC)", "formula": null, "molweight": 0.0, "casrn": "38797-88-5"}], "method": "Pressure decay sorption cell and procedure used are described in [1].", "reference": {"citation": "Fleming, G. K.; Koros, W. J.; Macromolecules 19, 2285 (1986).", "pubtype": "paper", "url": "https://doi.org/10.1021/ma00162a030"}, "dataset": [{"series": 1, "title": "Sorption isotherms of carbon dioxide in TMPC on a fugacity basis at 308 K (The original data were represented graphically)", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Sorption", "number": "1.353e+01", "significand": "1.353", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.1e-01", "significand": "2.1", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Sorption", "number": "2.609e+01", "significand": "2.609", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "6.0e-01", "significand": "6.0", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Sorption", "number": "3.548e+01", "significand": "3.548", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "9.8e-01", "significand": "9.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Sorption", "number": "4.217e+01", "significand": "4.217", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "1.33e+00", "significand": "1.33", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Sorption", "number": "4.841e+01", "significand": "4.841", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "1.65e+00", "significand": "1.65", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [], "data": [{"property": "Sorption", "number": "5.261e+01", "significand": "5.261", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "1.95e+00", "significand": "1.95", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 7, "conditions": [], "data": [{"property": "Sorption", "number": "5.750e+01", "significand": "5.750", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.26e+00", "significand": "2.26", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 8, "conditions": [], "data": [{"property": "Sorption", "number": "6.195e+01", "significand": "6.195", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.51e+00", "significand": "2.51", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 9, "conditions": [], "data": [{"property": "Sorption", "number": "6.481e+01", "significand": "6.481", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.77e+00", "significand": "2.77", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 10, "conditions": [], "data": [{"property": "Sorption", "number": "6.880e+01", "significand": "6.880", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "3.03e+00", "significand": "3.03", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 11, "conditions": [], "data": [{"property": "Sorption", "number": "7.190e+01", "significand": "7.190", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "3.27e+00", "significand": "3.27", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 12, "conditions": [], "data": [{"property": "Sorption", "number": "7.591e+01", "significand": "7.591", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "3.47e+00", "significand": "3.47", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 13, "conditions": [], "data": [{"property": "Sorption", "number": "8.036e+01", "significand": "8.036", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "3.72e+00", "significand": "3.72", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 14, "conditions": [], "data": [{"property": "Sorption", "number": "8.460e+01", "significand": "8.460", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "3.91e+00", "significand": "3.91", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 15, "conditions": [], "data": [{"property": "Sorption", "number": "8.839e+01", "significand": "8.839", 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