{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Eberius, E.; Wasserbestimmung mit Karl-Fischer-Losung (Verlag, GMBH, Weinheim, 1954), p. 67.", "pubtype": "book"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Distilled."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source and purity not given."}], "method": "A 50 g trichloromethane sample was shaken with pure water in a 100 mL Erlenmeyer flask. When equilibrium had been attained and the two phases separated, the organic phase was analyzed for water using the Karl-Fischer titration method. Five determinations were performed.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Percent mass fraction (1)", "number": "8.4e-02", "significand": "8.4", "exponent": "-2", "sigfigs": "2", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "5.54e-03", "significand": "5.54", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "4.66e-06", "significand": "4.66", "exponent": "-6", "sigfigs": "3", "unit": "mol/g"}]}]}]}}