{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "De Minjer, C. H.; Ph.D. Dissertation, Technische Hoogeschool, Delft, The Netherlands, 1939, 165 pp.", "pubtype": "dissertation"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Distilled."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Commercial grade, washed with $\\ce{H2SO4}$ and $\\ce{K2CO3}$ solutions, followed by distillation before use."}], "method": "Weighted mixtures of water and trichloromethane were shaken in sealed tubes in a water bath until the equilibrium had been established. After separation in two layers, a sample of the organic phase was taken and the water content of the mixture was determined by titration with a solution of cobalt chloride in anhydrous acetone. For further details, see [1].", "reference": {"citation": "Wilson, P. E.; J. Am. Chem. Soc. 1921, 43, 710.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01437a003"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Percent mass fraction (1)", "number": "2.0e-01", "significand": "2.0", "exponent": "-1", "sigfigs": "2", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "1.31e-02", "significand": "1.31", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "1.11e-04", "significand": "1.11", "exponent": "-4", "sigfigs": "3", "unit": "mol/g"}]}]}]}}