{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Clifford, C. W.; Ind. Eng. Chem. 1921, 13, 631-32.", "pubtype": "paper", "url": "https://doi.org/10.1021/ie50139a018"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Distilled (compiler)."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "U. S. P. grade, used after dehydration with $\\ce{CaCl2}$."}], "method": "The calcium chloride method was used for the determination of water in trichloromethane. The water was measured as the moisture abstracted from the samples by air and absorbed in two calcium chloride tubes. The tubes were weighed before and after absorption. For further details, see the paper by Clifford [1].", "reference": {"citation": "Clifford, C. W.; Ind. Eng. Chem. 1921, 13, 628.", "pubtype": "paper", "url": "https://doi.org/10.1021/ie50139a018"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.45e+01", "significand": "2.45", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Percent mass fraction (1)", "number": "8.4e-02", "significand": "8.4", "exponent": "-2", "sigfigs": "2", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "5.54e-04", "significand": "5.54", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "4.66e-05", "significand": "4.66", "exponent": "-5", "sigfigs": "3", "unit": "mol/g"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.66e+01", "significand": "2.66", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Percent mass fraction (1)", "number": "1.07e-01", "significand": "1.07", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "7.05e-04", "significand": "7.05", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "5.94e-05", "significand": "5.94", "exponent": "-5", "sigfigs": "3", "unit": "mol/g"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.78e+01", "significand": "2.78", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Percent mass fraction (1)", "number": "1.16e-01", "significand": "1.16", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "7.64e-04", "significand": "7.64", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "6.44e-05", "significand": "6.44", "exponent": "-5", "sigfigs": "3", "unit": "mol/g"}]}]}]}}