{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tribromomethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Warner, H. P.; Cohen, J. M.; Ireland, J. C.; 'Determination of Henry's Law Constants of Selected Priority Pollutants' U.S. EPA Technical Report, PB87-212684, Cincinnati, OH.; July 1987.", "pubtype": "report", "url": "https://ntrl.ntis.gov/NTRL/dashboard/searchResults/titleDetail/PB87212684.xhtml"}], "system": "Tribromomethane with Water", "substances": [{"constituent": 1, "name": "Tribromomethane", "formula": "CHBr3", "molweight": 252.731, "casrn": "75-25-2", "inchi": "InChI=1S/CHBr3/c2-1(3)4/h1H", "inchikey": "DIKBFYAXUHHXCS-UHFFFAOYSA-N", "sample": "Source not given. Purest quality available and was used without further purification, stated purity of > 99%."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "distilled and deionized."}], "method": "The original method and apparatus for the determination of Henry's law constants, described by Mackay et al. [1], were used. The general procedure was to add an excess quantity of tribromomethane to distilled deionized water and mix the system overnight. A portion of the solution was returned to the stripping vessel. Tribromomethane was stripped isothermally from the solution at a known gas flow rate. The Henry's law constant was calculated from the log of the concentration versus time plot. The experimental data values are averages of two or more replicates.", "reference": {"citation": "Mackay, D.; Shiu, W. Y.; Sutherland, R. D. Environ. Sci. Technol. 1979, 13, 333.", "pubtype": "paper", "url": "https://doi.org/10.1021/es60151a012"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.485e+01", "significand": "2.485", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "3.512e-01", "significand": "3.512", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "2.511e-04", "significand": "2.511", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "5.32e-04", "significand": "5.32", "exponent": "-4", "sigfigs": "3", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}]}]}}