{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 180) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Glenn T. Hefter", "sources": [{"citation": "Sanemasa, I.; Araki, M.; Deguchi, T.; Nagai, H.; Bull. Chem. Soc. Jpn. 1982, 55, 1054-62.", "pubtype": "paper", "url": "https://doi.org/10.1246/bcsj.55.1054"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Redistilled; no further details given."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "Analytical reagent grade (Wako Pure Chemical Ind. Ltd.), stated purity 99.5%, used without further purification."}], "method": "The apparatus is similar to an earlier design (ref 2) and is described in detail and in the paper. 100-200 cm<sup>3</sup> of (2) and 10-20 cm<sup>3</sup> of liquid (1) were placed in separate but connected thermostatted flasks. After thermal equilibrium was established a recirculating stream of air was used to vaporize liquid (1) and to transport the vapor to the flask containing (2). Five 10 cm<sup>3</sup> aliquots were withdrawn into separatory funnels. The concentration of (1) in (2) was then determined by extraction into chloroform followed by UV-spectrophotometry. Standards for the spectrophotometry were prepared by weight from pure liquid solutes.", "reference": {"citation": "Sanemasa, I.; Araki, M.; Deguchi, T.; Nagai, H.; Chem. Lett. 1981, 225-8.", "pubtype": "paper", "url": "https://doi.org/10.1246/cl.1981.225"}, "dataset": [{"series": 1, "title": "Solubility of benzene in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "5e+00", "significand": "5", "exponent": "0", "sigfigs": "1", "unit": "&deg;C"}], "data": [{"property": "Amount Concentration (1)", "number": "2.07e-02", "significand": "2.07", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "3.73e-04", "significand": "3.73", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.62e-01", "significand": "1.62", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount Concentration (1)", "number": "2.02e-02", "significand": "2.02", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "3.65e-04", "significand": "3.65", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.58e-01", "significand": "1.58", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount Concentration (1)", "number": "2.07e-02", "significand": "2.07", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "3.74e-04", "significand": "3.74", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.62e-01", "significand": "1.62", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.5e+01", "significand": "3.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount Concentration (1)", "number": "2.18e-02", "significand": "2.18", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "3.94e-04", "significand": "3.94", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.71e-01", "significand": "1.71", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "4.5e+01", "significand": "4.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Amount Concentration (1)", "number": "2.28e-02", "significand": "2.28", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.15e-04", "significand": "4.15", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.80e-01", "significand": "1.80", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}]}]}}