{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tribromomethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "McNally, M. E.; Grob, R. L.; J. Chromatogr. A 1984, 284, 105-16.", "pubtype": "paper", "url": "https://doi.org/10.1016/s0021-9673(01)87806-7"}], "system": "Tribromomethane with Water", "substances": [{"constituent": 1, "name": "Tribromomethane", "formula": "CHBr3", "molweight": 252.731, "casrn": "75-25-2", "inchi": "InChI=1S/CHBr3/c2-1(3)4/h1H", "inchikey": "DIKBFYAXUHHXCS-UHFFFAOYSA-N", "sample": "Chemical Service, West Chester, PA., USA., purest grade available."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled and run through two Barnstead purification cartridges."}], "method": "Standard tribromomethane solutions of increasing concentration were prepared in volumetric flasks as described elsewhere [1]. The aqueous organic liquid phase was 25 mL and the vapor phase above the mixture was 35 mL. The system was allowed to reach equilibrium in a constant temperature bath and then a sample was injected into the gas chromatograph. Values reported are an average of at least 5 measurements.", "reference": {"citation": "McNally, M. E.; Grob, R. L.; J. Chromatogr. A 1983, 260, 23-32.", "pubtype": "paper", "url": "https://doi.org/10.1016/0021-9673(83)80003-x"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "3.933e-01", "significand": "3.933", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "2.814e-04", "significand": "2.814", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}]}]}}