{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/2284/jsonld#"}], "@id": "", "generatedAt": "08-17-26 12:24:34", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/2284/jsonld#", "@type": "sdo:scidataFramework", "uid": "60_108", "title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Water-d2 with Tetrachloromethane", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Ari L. Horvath", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["Eidinoff, M. L. In \"Production of Heavy Water\", National Nuclear Energy Series Division III-Vol. 4F, Murphy, G. M.; Urey, H. C.; Kirshenbaum, I.; Eds.; McGraw-Hill: New York, 1955; Part II, Chapter 7, pp 129-44.", "afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:DEG_C", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "A 1 to 15 volume ratio mixture of heavy water and tetrachloromethane was introduced into an equilibration flask and then lowered into the water thermostat bath. The assembly was shaken mechanically for about 90 minutes at constant temperature. The amount of heavy water in the organic phase was determined by a modified Karl Fischer titration method. The determinations were done in triplicate. The description was taken from a secondary source [1]. The original report is not available from Columbia University.", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Eidinoff, M. L. In \"Production of Heavy Water\", National Nuclear Energy Series Division III-Vol. 4F, Murphy, G. M.; Urey, H. C.; Kirshenbaum, I.; Eds.; McGraw-Hill: New York, 1955; Part II, Chapter 7, pp 129-44."}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Tetrachloromethane", "formula": "CCl4", "casrn": "56-23-5", "iupacname": "tetrachloromethane", "inchikey": "VZGDMQKNWNREIO-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Water-d2", "formula": "D2O", "casrn": "7789-20-0", "inchikey": "XLYOFNOQVPJJNP-ZSJDYOACSA-N", "iupacname": "deuterated water"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Water-d2", "description": "Source and purity not given.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Tetrachloromethane", "description": "Source not given. Purified and dried before use.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Water-d2 with Tetrachloromethane", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.5e+01", "significand": 2.5, "exponent": 1, "sigfigs": 2}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "60:108:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Mole (1) per 100 gram", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.78e-04", "significand": 4.78, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.57e-03", "significand": 9.57, "exponent": -3, "sigfigs": 3}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.34e-04", "significand": 7.34, "exponent": -4, "sigfigs": 3}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Hutchinson, C. A.; Lyon, A. M.; Columbia University Report A-745, July 1, 1943."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 60 (page ?) - Water-d2 with Tetrachloromethane", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-60.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}