{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tetrachloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Kirchnerov\u00e1, J.; Cave, G. C. B.; Can. J. Chem. 1976, 54(24), 3909-16.", "pubtype": "paper", "url": "https://doi.org/10.1139/v76-562"}], "system": "Tetrachloromethane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Fisher - C199, washed with $\\ce{H2SO4}$ and $\\ce{K2CO3}$ solutions and finally with water. Dried over silica gel and fractionally distilled. Purity was better than 99.8%."}, {"constituent": 1, "name": "Tetrachloromethane", "formula": "CCl4", "molweight": 153.823, "casrn": "56-23-5", "inchi": "InChI=1S/CCl4/c2-1(3,4)5", "inchikey": "VZGDMQKNWNREIO-UHFFFAOYSA-N", "sample": "Distilled and deionized."}], "method": "A bottle containing a mixture of 50 mL tetrachloromethane and 6 mL water was submerged into a water thermostat bath for two days. The concentration of water in the organic phase was determined by a conventional Karl Fischer deadstop backtitration. The determination was carried out in triplicate. A detailed description of the complete procedure is given in a Ph.D. thesis [1].", "reference": {"citation": "Kirchnerova, J.; Ph. D. Thesis, McGill Univ.; Montreal, Quebec, April 1975, 280 pp.", "pubtype": "thesis"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "8.7e+00", "significand": "8.7", "exponent": "0", "sigfigs": "2", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.96e-03", "significand": "9.96", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "8.5e-04", "significand": "8.5", "exponent": "-4", "sigfigs": "2", "unit": "1"}]}]}]}}