{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tetrachloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Glasoe, P. K.; Schultz, S. D.; J. Chem. Eng. Data 1972, 17, 66-8.", "pubtype": "paper", "url": "https://doi.org/10.1021/je60052a025"}], "system": "Tetrachloromethane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source not given. Reagent grade, purified by distillation before use."}, {"constituent": 1, "name": "Tetrachloromethane", "formula": "CCl4", "molweight": 153.823, "casrn": "56-23-5", "inchi": "InChI=1S/CCl4/c2-1(3,4)5", "inchikey": "VZGDMQKNWNREIO-UHFFFAOYSA-N", "sample": "Distilled."}], "method": "The saturation of tetrachloromethane with water occurred in a closed system, protected from atmospheric moisture; the saturating vessel was placed in a constant temperature water bath. The concentration of water in tetrachloromethane was measured using the Karl Fischer titration method with a 'dead stop' end-point determination [1]. Fifteen observations were made at each temperature.", "reference": {"citation": "Wernimont, G.; Hopkinson, F. J. Ind. Eng. Chem., Anal. Ed. 1943, 272.", "pubtype": "paper", "url": "https://doi.org/10.1021/i560116a017"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "6.2e+00", "significand": "6.2", "exponent": "0", "sigfigs": "2", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.97e-03", "significand": "6.97", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.95e-04", "significand": "5.95", "exponent": "-4", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "8.6e+00", "significand": "8.6", "exponent": "0", "sigfigs": "2", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.78e-03", "significand": "9.78", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "8.35e-04", "significand": "8.35", "exponent": "-4", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "9.3e+00", "significand": "9.3", "exponent": "0", "sigfigs": "2", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.06e-02", "significand": "1.06", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "9.08e-04", "significand": "9.08", "exponent": "-4", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.5e+01", "significand": "3.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "1.14e+01", "significand": "1.14", "exponent": "1", "sigfigs": "3", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.31e-02", "significand": "1.31", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.12e-03", "significand": "1.12", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "4.5e+01", "significand": "4.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "1.56e+01", "significand": "1.56", "exponent": "1", "sigfigs": "3", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.82e-02", "significand": "1.82", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.55e-03", "significand": "1.55", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}]}]}}