{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichlorofluoromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Howe, G. B.; Mullins, M. E.; Rogers, T. N.; AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).", "pubtype": "report"}], "system": "Trichlorofluoromethane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled deionized."}, {"constituent": 1, "name": "Trichlorofluoromethane", "formula": "CCl3F", "molweight": 137.368, "casrn": "75-69-4", "inchi": "InChI=1S/CCl3F/c2-1(3,4)5", "inchikey": "CYRMSUTZVYGINF-UHFFFAOYSA-N", "sample": "Probably a commercial reagent, at least 99% purity, used as received."}], "method": "250 mL bottles were filled with distilled deionized water and sealed. Measured volumes of trichlorofluoromethane were injected into the bottles through each bottle septum using a microliter syringe. The solute was in excess of the anticipated solubility limit. The bottles were shaken for one hour with a wrist-action shaker and allowed to equilibrate for about three weeks. Samples were then injected into a gas chromatograph equipped with a Carbopack column and a FID detector. The GC responses were compared with a calibration plot to establish concentrations.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.0e+01", "significand": "1.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "5.41e-04", "significand": "5.41", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "5.41e-02", "significand": "5.41", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "7.098e-05", "significand": "7.098", "exponent": "-5", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "3.41e-04", "significand": "3.41", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "3.41e-02", "significand": "3.41", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.473e-05", "significand": "4.473", "exponent": "-5", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "2.62e-04", "significand": "2.62", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "2.62e-02", "significand": "2.62", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "3.437e-05", "significand": "3.437", "exponent": "-5", "sigfigs": "4", "unit": "1"}]}]}]}}