Yuri P. Yampol'skii
-1
2.0e-01
Ambient pressure
2
2.0
$\pu{MPa}$
-1
7.3e-01
Sorption
2
7.3
$\pu{V_{1}/V_{2}}$
1
-1
4.2e-01
Ambient pressure
2
4.2
$\pu{MPa}$
0
1.41e+00
Sorption
3
1.41
$\pu{V_{1}/V_{2}}$
2
-1
6.4e-01
Ambient pressure
2
6.4
$\pu{MPa}$
0
2.02e+00
Sorption
3
2.02
$\pu{V_{1}/V_{2}}$
3
-1
8.2e-01
Ambient pressure
2
8.2
$\pu{MPa}$
0
2.55e+00
Sorption
3
2.55
$\pu{V_{1}/V_{2}}$
4
0
1.02e+00
Ambient pressure
3
1.02
$\pu{MPa}$
0
3.03e+00
Sorption
3
3.03
$\pu{V_{1}/V_{2}}$
5
0
1.25e+00
Ambient pressure
3
1.25
$\pu{MPa}$
0
3.62e+00
Sorption
3
3.62
$\pu{V_{1}/V_{2}}$
6
-1
2.6e-01
Ambient pressure
2
2.6
$\pu{MPa}$
-1
5.5e-01
Sorption
2
5.5
$\pu{V_{1}/V_{2}}$
7
-1
2.7e-01
Ambient pressure
2
2.7
$\pu{MPa}$
-1
5.9e-01
Sorption
2
5.9
$\pu{V_{1}/V_{2}}$
8
-1
5.5e-01
Ambient pressure
2
5.5
$\pu{MPa}$
0
1.12e+00
Sorption
3
1.12
$\pu{V_{1}/V_{2}}$
9
-1
6.6e-01
Ambient pressure
2
6.6
$\pu{MPa}$
0
1.40e+00
Sorption
3
1.40
$\pu{V_{1}/V_{2}}$
10
-1
8.1e-01
Ambient pressure
2
8.1
$\pu{MPa}$
0
1.60e+00
Sorption
3
1.60
$\pu{V_{1}/V_{2}}$
11
-1
9.7e-01
Ambient pressure
2
9.7
$\pu{MPa}$
0
1.91e+00
Sorption
3
1.91
$\pu{V_{1}/V_{2}}$
12
0
1.24e+00
Ambient pressure
3
1.24
$\pu{MPa}$
0
2.45e+00
Sorption
3
2.45
$\pu{V_{1}/V_{2}}$
13
0
1.43e+00
Ambient pressure
3
1.43
$\pu{MPa}$
0
4.11e+00
Sorption
3
4.11
$\pu{V_{1}/V_{2}}$
14
0
1.63e+00
Ambient pressure
3
1.63
$\pu{MPa}$
0
4.50e+00
Sorption
3
4.50
$\pu{V_{1}/V_{2}}$
15
0
1.85e+00
Ambient pressure
3
1.85
$\pu{MPa}$
0
5.05e+00
Sorption
3
5.05
$\pu{V_{1}/V_{2}}$
16
0
2.06e+00
Ambient pressure
3
2.06
$\pu{MPa}$
0
5.62e+00
Sorption
3
5.62
$\pu{V_{1}/V_{2}}$
17
0
2.28e+00
Ambient pressure
3
2.28
$\pu{MPa}$
0
5.95e+00
Sorption
3
5.95
$\pu{V_{1}/V_{2}}$
18
0
2.47e+00
Ambient pressure
3
2.47
$\pu{MPa}$
0
6.19e+00
Sorption
3
6.19
$\pu{V_{1}/V_{2}}$
19
0
1.37e+00
Ambient pressure
3
1.37
$\pu{MPa}$
0
2.65e+00
Sorption
3
2.65
$\pu{V_{1}/V_{2}}$
20
0
1.43e+00
Ambient pressure
3
1.43
$\pu{MPa}$
0
2.81e+00
Sorption
3
2.81
$\pu{V_{1}/V_{2}}$
21
0
1.74e+00
Ambient pressure
3
1.74
$\pu{MPa}$
0
3.29e+00
Sorption
3
3.29
$\pu{V_{1}/V_{2}}$
22
0
1.96e+00
Ambient pressure
3
1.96
$\pu{MPa}$
0
3.62e+00
Sorption
3
3.62
$\pu{V_{1}/V_{2}}$
23
0
2.19e+00
Ambient pressure
3
2.19
$\pu{MPa}$
0
4.16e+00
Sorption
3
4.16
$\pu{V_{1}/V_{2}}$
24
0
2.29e+00
Ambient pressure
3
2.29
$\pu{MPa}$
0
4.14e+00
Sorption
3
4.14
$\pu{V_{1}/V_{2}}$
25
0
2.50e+00
Ambient pressure
3
2.50
$\pu{MPa}$
0
4.51e+00
Sorption
3
4.51
$\pu{V_{1}/V_{2}}$
26
0
2.71e+00
Ambient pressure
3
2.71
$\pu{MPa}$
0
6.85e+00
Sorption
3
6.85
$\pu{V_{1}/V_{2}}$
27
0
2.90e+00
Ambient pressure
3
2.90
$\pu{MPa}$
0
7.18e+00
Sorption
3
7.18
$\pu{V_{1}/V_{2}}$
28
0
3.33e+00
Ambient pressure
3
3.33
$\pu{MPa}$
0
8.10e+00
Sorption
3
8.10
$\pu{V_{1}/V_{2}}$
29
0
3.39e+00
Ambient pressure
3
3.39
$\pu{MPa}$
0
8.27e+00
Sorption
3
8.27
$\pu{V_{1}/V_{2}}$
30
0
2.67e+00
Ambient pressure
3
2.67
$\pu{MPa}$
0
4.89e+00
Sorption
3
4.89
$\pu{V_{1}/V_{2}}$
31
0
2.76e+00
Ambient pressure
3
2.76
$\pu{MPa}$
0
4.99e+00
Sorption
3
4.99
$\pu{V_{1}/V_{2}}$
32
0
3.00e+00
Ambient pressure
3
3.00
$\pu{MPa}$
0
5.39e+00
Sorption
3
5.39
$\pu{V_{1}/V_{2}}$
33
0
3.29e+00
Ambient pressure
3
3.29
$\pu{MPa}$
0
5.83e+00
Sorption
3
5.83
$\pu{V_{1}/V_{2}}$
34
0
3.30e+00
Ambient pressure
3
3.30
$\pu{MPa}$
0
5.89e+00
Sorption
3
5.89
$\pu{V_{1}/V_{2}}$
35
0
3.37e+00
Ambient pressure
3
3.37
$\pu{MPa}$
0
6.42e+00
Sorption
3
6.42
$\pu{V_{1}/V_{2}}$
36
0
3.67e+00
Ambient pressure
3
3.67
$\pu{MPa}$
0
6.42e+00
Sorption
3
6.42
$\pu{V_{1}/V_{2}}$
39
2
Table 2. Sorption isotherms of methane in PEMA at 298 K (a) and 318 K (b) (The original data were represented graphically)
-1
2.7e-01
Ambient pressure
2
2.7
$\pu{MPa}$
-1
3.3e-01
Sorption
2
3.3
$\pu{V_{1}/V_{2}}$
1
-1
3.9e-01
Ambient pressure
2
3.9
$\pu{MPa}$
-1
4.8e-01
Sorption
2
4.8
$\pu{V_{1}/V_{2}}$
2
-1
5.0e-01
Ambient pressure
2
5.0
$\pu{MPa}$
-1
6.1e-01
Sorption
2
6.1
$\pu{V_{1}/V_{2}}$
3
-1
7.7e-01
Ambient pressure
2
7.7
$\pu{MPa}$
-1
9.4e-01
Sorption
2
9.4
$\pu{V_{1}/V_{2}}$
4
-1
8.5e-01
Ambient pressure
2
8.5
$\pu{MPa}$
0
1.07e+00
Sorption
3
1.07
$\pu{V_{1}/V_{2}}$
5
0
1.04e+00
Ambient pressure
3
1.04
$\pu{MPa}$
0
1.22e+00
Sorption
3
1.22
$\pu{V_{1}/V_{2}}$
6
0
1.26e+00
Ambient pressure
3
1.26
$\pu{MPa}$
0
1.51e+00
Sorption
3
1.51
$\pu{V_{1}/V_{2}}$
7
0
1.40e+00
Ambient pressure
3
1.40
$\pu{MPa}$
0
1.68e+00
Sorption
3
1.68
$\pu{V_{1}/V_{2}}$
8
0
1.61e+00
Ambient pressure
3
1.61
$\pu{MPa}$
0
1.94e+00
Sorption
3
1.94
$\pu{V_{1}/V_{2}}$
9
0
1.75e+00
Ambient pressure
3
1.75
$\pu{MPa}$
0
2.05e+00
Sorption
3
2.05
$\pu{V_{1}/V_{2}}$
10
0
1.98e+00
Ambient pressure
3
1.98
$\pu{MPa}$
0
2.25e+00
Sorption
3
2.25
$\pu{V_{1}/V_{2}}$
11
0
2.04e+00
Ambient pressure
3
2.04
$\pu{MPa}$
0
2.42e+00
Sorption
3
2.42
$\pu{V_{1}/V_{2}}$
12
0
2.27e+00
Ambient pressure
3
2.27
$\pu{MPa}$
0
2.66e+00
Sorption
3
2.66
$\pu{V_{1}/V_{2}}$
13
0
2.45e+00
Ambient pressure
3
2.45
$\pu{MPa}$
0
2.77e+00
Sorption
3
2.77
$\pu{V_{1}/V_{2}}$
14
0
2.79e+00
Ambient pressure
3
2.79
$\pu{MPa}$
0
3.21e+00
Sorption
3
3.21
$\pu{V_{1}/V_{2}}$
15
0
2.85e+00
Ambient pressure
3
2.85
$\pu{MPa}$
0
3.21e+00
Sorption
3
3.21
$\pu{V_{1}/V_{2}}$
16
0
3.29e+00
Ambient pressure
3
3.29
$\pu{MPa}$
0
3.69e+00
Sorption
3
3.69
$\pu{V_{1}/V_{2}}$
17
0
3.43e+00
Ambient pressure
3
3.43
$\pu{MPa}$
0
3.82e+00
Sorption
3
3.82
$\pu{V_{1}/V_{2}}$
18
0
3.68e+00
Ambient pressure
3
3.68
$\pu{MPa}$
0
4.08e+00
Sorption
3
4.08
$\pu{V_{1}/V_{2}}$
19
-1
2.5e-01
Ambient pressure
2
2.5
$\pu{MPa}$
-1
7.0e-01
Sorption
2
7.0
$\pu{V_{1}/V_{2}}$
20
-1
5.1e-01
Ambient pressure
2
5.1
$\pu{MPa}$
0
1.29e+00
Sorption
3
1.29
$\pu{V_{1}/V_{2}}$
21
-1
7.5e-01
Ambient pressure
2
7.5
$\pu{MPa}$
0
1.89e+00
Sorption
3
1.89
$\pu{V_{1}/V_{2}}$
22
0
1.02e+00
Ambient pressure
3
1.02
$\pu{MPa}$
0
2.44e+00
Sorption
3
2.44
$\pu{V_{1}/V_{2}}$
23
0
1.34e+00
Ambient pressure
3
1.34
$\pu{MPa}$
0
3.20e+00
Sorption
3
3.20
$\pu{V_{1}/V_{2}}$
24
0
1.52e+00
Ambient pressure
3
1.52
$\pu{MPa}$
0
3.44e+00
Sorption
3
3.44
$\pu{V_{1}/V_{2}}$
25
0
1.82e+00
Ambient pressure
3
1.82
$\pu{MPa}$
0
4.15e+00
Sorption
3
4.15
$\pu{V_{1}/V_{2}}$
26
0
2.14e+00
Ambient pressure
3
2.14
$\pu{MPa}$
0
4.63e+00
Sorption
3
4.63
$\pu{V_{1}/V_{2}}$
28
0
2.23e+00
Ambient pressure
3
2.23
$\pu{MPa}$
0
5.00e+00
Sorption
3
5.00
$\pu{V_{1}/V_{2}}$
29
0
2.60e+00
Ambient pressure
3
2.60
$\pu{MPa}$
0
5.57e+00
Sorption
3
5.57
$\pu{V_{1}/V_{2}}$
30
0
2.83e+00
Ambient pressure
3
2.83
$\pu{MPa}$
0
6.01e+00
Sorption
3
6.01
$\pu{V_{1}/V_{2}}$
31
0
3.09e+00
Ambient pressure
3
3.09
$\pu{MPa}$
0
6.42e+00
Sorption
3
6.42
$\pu{V_{1}/V_{2}}$
32
0
3.20e+00
Ambient pressure
3
3.20
$\pu{MPa}$
0
6.71e+00
Sorption
3
6.71
$\pu{V_{1}/V_{2}}$
33
0
3.54e+00
Ambient pressure
3
3.54
$\pu{MPa}$
0
7.34e+00
Sorption
3
7.34
$\pu{V_{1}/V_{2}}$
34
-1
3.3e-01
Ambient pressure
2
3.3
$\pu{MPa}$
-1
9.0e-01
Sorption
2
9.0
$\pu{V_{1}/V_{2}}$
35
-1
5.2e-01
Ambient pressure
2
5.2
$\pu{MPa}$
0
1.38e+00
Sorption
3
1.38
$\pu{V_{1}/V_{2}}$
36
-1
6.1e-01
Ambient pressure
2
6.1
$\pu{MPa}$
0
1.62e+00
Sorption
3
1.62
$\pu{V_{1}/V_{2}}$
37
-1
7.7e-01
Ambient pressure
2
7.7
$\pu{MPa}$
0
2.02e+00
Sorption
3
2.02
$\pu{V_{1}/V_{2}}$
38
-1
9.2e-01
Ambient pressure
2
9.2
$\pu{MPa}$
0
2.30e+00
Sorption
3
2.30
$\pu{V_{1}/V_{2}}$
39
0
1.03e+00
Ambient pressure
3
1.03
$\pu{MPa}$
0
2.70e+00
Sorption
3
2.70
$\pu{V_{1}/V_{2}}$
40
0
1.28e+00
Ambient pressure
3
1.28
$\pu{MPa}$
0
3.09e+00
Sorption
3
3.09
$\pu{V_{1}/V_{2}}$
41
0
1.42e+00
Ambient pressure
3
1.42
$\pu{MPa}$
0
3.47e+00
Sorption
3
3.47
$\pu{V_{1}/V_{2}}$
42
0
1.62e+00
Ambient pressure
3
1.62
$\pu{MPa}$
0
3.75e+00
Sorption
3
3.75
$\pu{V_{1}/V_{2}}$
43
0
2.00e+00
Ambient pressure
3
2.00
$\pu{MPa}$
0
4.47e+00
Sorption
3
4.47
$\pu{V_{1}/V_{2}}$
44
0
2.07e+00
Ambient pressure
3
2.07
$\pu{MPa}$
0
4.69e+00
Sorption
3
4.69
$\pu{V_{1}/V_{2}}$
45
0
2.33e+00
Ambient pressure
3
2.33
$\pu{MPa}$
0
5.2e+00
Sorption
2
5.2
$\pu{V_{1}/V_{2}}$
46
0
2.53e+00
Ambient pressure
3
2.53
$\pu{MPa}$
0
5.28e+00
Sorption
3
5.28
$\pu{V_{1}/V_{2}}$
47
0
2.73e+00
Ambient pressure
3
2.73
$\pu{MPa}$
0
5.66e+00
Sorption
3
5.66
$\pu{V_{1}/V_{2}}$
48
0
2.76e+00
Ambient pressure
3
2.76
$\pu{MPa}$
0
5.90e+00
Sorption
3
5.90
$\pu{V_{1}/V_{2}}$
49
-1
2.8e-01
Ambient pressure
2
2.8
$\pu{MPa}$
-1
1.7e-01
Sorption
2
1.7
$\pu{V_{1}/V_{2}}$
50
-1
3.4e-01
Ambient pressure
2
3.4
$\pu{MPa}$
-1
2.6e-01
Sorption
2
2.6
$\pu{V_{1}/V_{2}}$
51
-1
6.2e-01
Ambient pressure
2
6.2
$\pu{MPa}$
-1
4.1e-01
Sorption
2
4.1
$\pu{V_{1}/V_{2}}$
52
-1
6.8e-01
Ambient pressure
2
6.8
$\pu{MPa}$
-1
4.6e-01
Sorption
2
4.6
$\pu{V_{1}/V_{2}}$
53
-1
9.0e-01
Ambient pressure
2
9.0
$\pu{MPa}$
-1
5.9e-01
Sorption
2
5.9
$\pu{V_{1}/V_{2}}$
54
0
1.05e+00
Ambient pressure
3
1.05
$\pu{MPa}$
-1
6.1e-01
Sorption
2
6.1
$\pu{V_{1}/V_{2}}$
55
0
1.45e+00
Ambient pressure
3
1.45
$\pu{MPa}$
-1
8.7e-01
Sorption
2
8.7
$\pu{V_{1}/V_{2}}$
56
0
1.56e+00
Ambient pressure
3
1.56
$\pu{MPa}$
-1
9.5e-01
Sorption
2
9.5
$\pu{V_{1}/V_{2}}$
57
0
1.62e+00
Ambient pressure
3
1.62
$\pu{MPa}$
-1
9.5e-01
Sorption
2
9.5
$\pu{V_{1}/V_{2}}$
58
0
1.89e+00
Ambient pressure
3
1.89
$\pu{MPa}$
0
1.10e+00
Sorption
3
1.10
$\pu{V_{1}/V_{2}}$
59
0
2.11e+00
Ambient pressure
3
2.11
$\pu{MPa}$
0
1.23e+00
Sorption
3
1.23
$\pu{V_{1}/V_{2}}$
60
0
2.25e+00
Ambient pressure
3
2.25
$\pu{MPa}$
0
1.34e+00
Sorption
3
1.34
$\pu{V_{1}/V_{2}}$
61
0
2.32e+00
Ambient pressure
3
2.32
$\pu{MPa}$
0
1.39e+00
Sorption
3
1.39
$\pu{V_{1}/V_{2}}$
62
0
2.63e+00
Ambient pressure
3
2.63
$\pu{MPa}$
0
1.54e+00
Sorption
3
1.54
$\pu{V_{1}/V_{2}}$
63
0
2.83e+00
Ambient pressure
3
2.83
$\pu{MPa}$
0
1.62e+00
Sorption
3
1.62
$\pu{V_{1}/V_{2}}$
64
0
2.91e+00
Ambient pressure
3
2.91
$\pu{MPa}$
0
1.73e+00
Sorption
3
1.73
$\pu{V_{1}/V_{2}}$
65
0
3.16e+00
Ambient pressure
3
3.16
$\pu{MPa}$
0
1.86e+00
Sorption
3
1.86
$\pu{V_{1}/V_{2}}$
66
0
3.39e+00
Ambient pressure
3
3.39
$\pu{MPa}$
0
2.03e+00
Sorption
3
2.03
$\pu{V_{1}/V_{2}}$
67
0
3.53e+00
Ambient pressure
3
3.53
$\pu{MPa}$
0
1.99e+00
Sorption
3
1.99
$\pu{V_{1}/V_{2}}$
68
0
3.67e+00
Ambient pressure
3
3.67
$\pu{MPa}$
0
2.21e+00
Sorption
3
2.21
$\pu{V_{1}/V_{2}}$
69
0
3.78e+00
Ambient pressure
3
3.78
$\pu{MPa}$
0
2.21e+00
Sorption
3
2.21
$\pu{V_{1}/V_{2}}$
70
3
Table 3. Sorption isotherms of various gases in PEMA at 308 K (The original data were represented graphically)
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
1.83e-01
Henry's Law Solubility Coefficient
3
1.83
$\pu{cm3(g) cm-3(s) atm-1}$
0
2.87e+00
Langmuir sorption capacity parameter
3
2.87
$\pu{cm3/cm3}$
-2
6.77e-02
Affinity Coefficient
3
6.77
$\pu{atm-1}$
1
2
3.08e+02
Ambient temperature
3
3.08
$\pu{K}$
-1
1.65e-01
Henry's Law Solubility Coefficient
3
1.65
$\pu{cm3(g) cm-3(s) atm-1}$
0
2.24e+00
Langmuir sorption capacity parameter
3
2.24
$\pu{cm3/cm3}$
-2
5.36e-02
Affinity Coefficient
3
5.36
$\pu{atm-1}$
2
2
3.13e+02
Ambient temperature
3
3.13
$\pu{K}$
-1
1.44e-01
Henry's Law Solubility Coefficient
3
1.44
$\pu{cm3(g) cm-3(s) atm-1}$
0
1.87e+00
Langmuir sorption capacity parameter
3
1.87
$\pu{cm3/cm3}$
-2
4.22e-02
Affinity Coefficient
3
4.22
$\pu{atm-1}$
3
2
3.08e+02
Ambient temperature
3
3.08
$\pu{K}$
-2
9.02e-02
Henry's Law Solubility Coefficient
3
9.02
$\pu{cm3(g) cm-3(s) atm-1}$
0
1.20e+00
Langmuir sorption capacity parameter
3
1.20
$\pu{cm3/cm3}$
-2
4.05e-02
Affinity Coefficient
3
4.05
$\pu{atm-1}$
4
1
Table 1. Dual mode sorption parameters for methane and argon in PEMA
Solubility, Solubility data series
Sorption isotherms were measured by the pressure decay method using a dual volume sorption cell.
The International Union of Pure and Applied Chemistry
Chiou, J. S.; Paul, D. R.; J. Membr. Sci. 45, 167 (1989).
paper
https://doi.org/10.1016/s0376-7388(00)80852-2
97-63-2
2
(C6H802)n
InChI=1S/C6H10O2/c1-4-8-6(7)5(2)3/h2,4H2,1,3H3
SUPCQIBBMFXVTL-UHFFFAOYSA-N
114.14
Poly(ethyl methacrylate) (PEMA)
PEMA: DuPont Co. (Elvacite 2042). $M_{\rm{w}}$ = 438 000, $T_{\rm{g}}$ = 342 K (DSC method).
1
$\ce{Ar}$, $\ce{N2}$, $\ce{CO2}$ and $\ce{CH4}$
0.0
Various gases (x4)
Various gases (x4) and Poly(ethyl methacrylate) (PEMA)
Solubility data from IUPAC SDS Volume 70 (page ?) - Various gases (x4) and Poly(ethyl methacrylate) (PEMA)