{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Howe, G. B.; Mullins, M. E.; Rogers, T. N.; AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).", "pubtype": "report"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Probable a commercial reagent at least 99% purity. Used as received."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "distilled and deionized."}], "method": "250 cm<sup>3</sup> bottles were filled with distilled deionized water and sealed. A measured volume of trichloromethane was injected into the bottles through each bottle septum using a microliter syringe. Trichloromethane was in excess of the anticipated solubility limit. The bottles were shaken for 1 hour with a wrist-action shaker and allowed to equilibrate for about 3 weeks. Samples were then injected into a gas chromatograph equipped with a Carbopack column and a FID detector. The GC response was compared with the calibration plot.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.0e+01", "significand": "1.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mass fraction (1)", "number": "3.471e-03", "significand": "3.471", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "3.471e-01", "significand": "3.471", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.2535e-04", "significand": "5.2535", "exponent": "-4", "sigfigs": "5", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mass fraction (1)", "number": "2.963e-03", "significand": "2.963", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "2.963e-01", "significand": "2.963", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.4827e-04", "significand": "4.4827", "exponent": "-4", "sigfigs": "5", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mass fraction (1)", "number": "3.596e-03", "significand": "3.596", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "3.596e-01", "significand": "3.596", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.4432e-04", "significand": "5.4432", "exponent": "-4", "sigfigs": "5", "unit": "1"}]}]}]}}