{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Takano, J.; Ishihara, Y.; Yasuoka, T.; Mitsuzawa, S.; Nippon Kagaku Kaishi, 1985, 2116-9.", "pubtype": "paper", "url": "https://doi.org/10.1246/nikkashi.1985.2116"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Tokyo Chemical Co., analytical grade reagent, redistilled before use."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Double distilled."}], "method": "A mixture of 1 cm<sup>3</sup> trichloromethane and 30 cm<sup>3</sup> water was introduced into a centrifuge tube which was then shaken for 60 minutes in a shaker at room temperature. After an additional shaking of 48 hours, samples were filtered through four types of filter paper in order to free the solution from emulsions. The concentrations of the aqueous solutions were determined by the TOC (Total Organic Carbon) method. Nine measurements were performed for each solution.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}, {"property": "Mass density", "number": "7.77e+00", "significand": "7.77", "exponent": "0", "sigfigs": "3", "unit": "g/L"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "7.770e-01", "significand": "7.770", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.180e-03", "significand": "1.180", "exponent": "-3", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}, {"property": "Mass density", "number": "9.33e+00", "significand": "9.33", "exponent": "0", "sigfigs": "3", "unit": "g/L"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.330e-01", "significand": "9.330", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.419e-03", "significand": "1.419", "exponent": "-3", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}, {"property": "Mass density", "number": "6.33e+00", "significand": "6.33", "exponent": "0", "sigfigs": "3", "unit": "g/L"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.330e-01", "significand": "6.330", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "9.604e-04", "significand": "9.604", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}, {"property": "Mass density", "number": "8.55e+00", "significand": "8.55", "exponent": "0", "sigfigs": "3", "unit": "g/L"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "8.550e-01", "significand": "8.550", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.300e-03", "significand": "1.300", "exponent": "-3", "sigfigs": "4", "unit": "1"}]}]}]}}