{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/3367/jsonld#"}], "@id": "", "generatedAt": "10-19-26 06:47:02", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/3367/jsonld#", "@type": "sdo:scidataFramework", "uid": "67_44", "title": "Solubility data from IUPAC SDS Volume 67 (page 428) - Tetrachloroethene with Ammonium carbonate and Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Ari L. Horvath", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afq:AFQ_0000168", "afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "obo:NCIT_C75762", "qudt:DEG_C", "qudt:GM-PER-M3", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The aqueous electrolyte solutions were saturated with tetrachloroethene in thermostated flasks fitted with stirrers and a mercury seal. Stirring was continued for several days until equilibrium was established. Samples were taken at specific time intervals to check for equilibrium. The concentration of tertachloroethene in the aqueous phase was measured by gas chromatography.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Tetrachloroethene", "formula": "C2Cl4", "casrn": "127-18-4", "iupacname": "1,1,2,2-tetrachloroethene", "inchikey": "CYTYCFOTNPOANT-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Ammonium carbonate", "formula": "(NH4)2CO3", "casrn": "506-87-6", "iupacname": "azane;carbonic acid", "inchikey": "PRKQVKDSMLBJBJ-UHFFFAOYSA-N"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Tetrachloroethene", "description": "Type \"pure\" (MRTU 6-00 No. 6590-70), redistilled and checked by GC before use.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Ammonium carbonate", "description": "Type \"chemically pure\".", "substance#": "substance/2/"}, {"@id": "chemical/3/", "@type": "sdo:chemical", "name": "Water", "description": "Distilled.", "substance#": "substance/3/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Tetrachloroethene with Ammonium carbonate and Water", "type": "ternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "quantity/2/", "@type": "sdo:quantity", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "unit": "Gram per meter cubed", "unit#": "qudt:GM-PER-M3"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.0e+01", "significand": 2.0, "exponent": 1, "sigfigs": 2}, {"@id": "condition/2/", "@type": "sdo:condition", "quantity#": "quantity/2/", "number": "1.000e+02", "significand": 1.0, "exponent": 2, "sigfigs": 4, "error": "0.056", "errornote": "absolute"}, {"@id": "condition/3/", "@type": "sdo:condition", "quantity#": "quantity/2/", "number": "7.88e+01", "significand": 7.88, "exponent": 1, "sigfigs": 3, "error": "0.013", "errornote": "absolute"}, {"@id": "condition/4/", "@type": "sdo:condition", "quantity#": "quantity/2/", "number": "7.72e+01", "significand": 7.72, "exponent": 1, "sigfigs": 3, "error": "0.018", "errornote": "absolute"}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "67:044:001:001:001", "conditions#": ["condition/1/", "condition/4/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.00e-03", "significand": 1.0, "exponent": -3, "sigfigs": 3}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.6e-03", "significand": 9.6, "exponent": -3, "sigfigs": 2}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "67:044:001:001:002", "conditions#": ["condition/2/", "condition/5/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.62e-03", "significand": 1.62, "exponent": -3, "sigfigs": 3}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.5e-03", "significand": 7.5, "exponent": -3, "sigfigs": 2}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "67:044:001:001:003", "conditions#": ["condition/3/", "condition/6/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.10e-03", "significand": 2.1, "exponent": -3, "sigfigs": 3}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.0e-03", "significand": 7.0, "exponent": -3, "sigfigs": 2}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Moiseeva, L. M.; Stepanova, G. G.; Pukhonto, A. N.; Sov. Chem. Ind. 9, 453 (1977)."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 67 (page 428) - Tetrachloroethene with Ammonium carbonate and Water", "url": "https://doi.org/10.1063/1.556039"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}