{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Iodomethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Swain, C. G.; Thornton, E. R.; J. Am. Chem. Soc. 1962, 84, 822-6.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja00864a029"}], "system": "Iodomethane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Double distilled."}, {"constituent": 1, "name": "Iodomethane", "formula": "CH3I", "molweight": 141.939, "casrn": "74-88-4", "inchi": "InChI=1S/CH3I/c1-2/h1H3", "inchikey": "INQOMBQAUSQDDS-UHFFFAOYSA-N", "sample": "Eastman Kodak Co., redistilled before use."}], "method": "The measuring apparatus was described by Brown, et al. [1]. Iodomethane gas was admitted to the measurement apparatus from a storage bulb by distillation. The gas volume absorbed by water was determined using a gas buret. The temperature was controlled by a water bath and the equilibrium was aided by a magnetic stirrer in the equilibration bulb. The concentration in the solution was calculated from the pressure and volume measured.", "reference": {"citation": "Brown, H. C.; Taylor, M. D.; Gerstein, M. J.; Am. Chem. Soc. 1944, 66, 431.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01231a038"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.944e+01", "significand": "2.944", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}], "data": [{"property": "Solubility (Pressure per concentration)", "number": "4.88e+03", "significand": "4.88", "exponent": "3", "sigfigs": "3", "unit": "mmHg dm^3 mol^-1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.397e+00", "significand": "1.397", "exponent": "0", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.793e-03", "significand": "1.793", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "6.421e-03", "significand": "6.421", "exponent": "-3", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.945e+01", "significand": "2.945", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}], "data": [{"property": "Solubility (Pressure per concentration)", "number": "4.9e+03", "significand": "4.9", "exponent": "3", "sigfigs": "2", "unit": "mmHg dm^3 mol^-1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.392e+00", "significand": "1.392", "exponent": "0", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.788e-03", "significand": "1.788", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "6.447e-03", "significand": "6.447", "exponent": "-3", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "4.034e+01", "significand": "4.034", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}], "data": [{"property": "Solubility (Pressure per concentration)", "number": "6.85e+03", "significand": "6.85", "exponent": "3", "sigfigs": "3", "unit": "mmHg dm^3 mol^-1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.478e+00", "significand": "1.478", "exponent": "0", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.900e-03", "significand": "1.900", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "9.013e-03", "significand": "9.013", "exponent": "-3", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "4.035e+01", "significand": "4.035", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}], "data": [{"property": "Solubility (Pressure per concentration)", "number": "6.92e+03", "significand": "6.92", "exponent": "3", "sigfigs": "3", "unit": "mmHg dm^3 mol^-1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.463e+00", "significand": "1.463", "exponent": "0", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.881e-03", "significand": "1.881", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "9.105e-03", "significand": "9.105", "exponent": "-3", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}]}]}}