{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Diiodomethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Andrews, L. J.; Keefer, R. M.; J. Am. Chem. Soc. 1951, 73, 5733-6.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01156a072"}], "system": "Diiodomethane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled (compiler)."}, {"constituent": 1, "name": "Diiodomethane", "formula": "CH2I2", "molweight": 267.836, "casrn": "75-11-6", "inchi": "InChI=1S/CH2I2/c2-1-3/h1H2", "inchikey": "NZZFYRREKKOMAT-UHFFFAOYSA-N", "sample": "Prepared from iodoform at the University of California; BP = 71.0 - 71.5°C at 18 mmHg."}], "method": "Water was mixed with diiodomethanme in a glass-stoppered Erlenmeyer flask which was then placed in a constant temperature bath and rotated for 30 hours. The organic halide content of the aqueous solution was extracted with n-hexane. The optical density of the extract was measured against a nhexane blank using a Beckman spectrophotometer [1].", "reference": {"citation": "Andrews, L. J.; Keefer, R. M.; J. Am. Chem. Soc. 1949, 71, 3644-77.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01179a018"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "3.11e+00", "significand": "3.11", "exponent": "0", "sigfigs": "3", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "8.35e-02", "significand": "8.35", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.62e-05", "significand": "5.62", "exponent": "-5", "sigfigs": "3", "unit": "1"}]}]}]}}