{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Hydrogen chloride and Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Svetlanov, E. B.; Velichko, S. M.; Levinskii, M. I.; Treger, Yu. A.; Flid, R. M.; Russ. J. Phys. Chem. 1971, 45, 488-90.", "pubtype": "paper"}], "system": "Trichloromethane with Hydrogen chloride and Water", "substances": [{"constituent": 2, "name": "Hydrogen chloride", "formula": "HCl", "molweight": 36.461, "casrn": "7647-01-0", "inchi": "InChI=1S/ClH/h1H", "inchikey": "VEXZGXHMUGYJMC-UHFFFAOYSA-N", "sample": "Source and purity not given."}, {"constituent": 3, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled (compiler)."}, {"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Source and purity not given."}], "method": "The dynamic method which was used for the solubility determination consisted of the saturation of nitrogen with the solute vapor which was then bubbled through a thermostatically controlled flask filled with a definite volume of trichloromethane. After 2- 3 hours, the solution became saturated and samples were taken periodically [1]. The trichloromethane concentration in the aqueous solution was determined by GLC. On average, 3 - 5 measurements were taken at each temperature.", "reference": {"citation": "Treger, Yu. A.; Flid, R. M.; Spektor, S. S.; Russ. J. Phys. Chem. 38. 253 (1964)", "pubtype": "paper"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "6.70e-03", "significand": "6.70", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.70e-01", "significand": "6.70", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.0710000000000001e-03", "significand": "1.0710000000000002", "exponent": "-3", "sigfigs": "17", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "4.44e-03", "significand": "4.44", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "4.44e-01", "significand": "4.44", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "7.086e-04", "significand": "7.086", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "4.5e+01", "significand": "4.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "2.36e-03", "significand": "2.36", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "2.36e-01", "significand": "2.36", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "3.759e-04", "significand": "3.759", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "6.0e+01", "significand": "6.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "1.34e-03", "significand": "1.34", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.34e-01", "significand": "1.34", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "2.132e-04", "significand": "2.132", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "9.20e-03", "significand": "9.20", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.20e-01", "significand": "9.20", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.558e-03", "significand": "1.558", "exponent": "-3", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "5.16e-03", "significand": "5.16", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "5.16e-01", "significand": "5.16", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "8.706e-04", "significand": "8.706", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "4.5e+01", "significand": "4.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "2.84e-03", "significand": "2.84", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "2.84e-01", "significand": "2.84", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.781e-04", "significand": "4.781", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "6.0e+01", "significand": "6.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "1.50e-03", "significand": "1.50", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.50e-01", "significand": "1.50", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "2.522e-04", "significand": "2.522", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}]}]}}