{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Hunter-Smith, R. J.; Balls, P. W.; Liss, P. S.; Tellus 35B, 170 (1983).", "pubtype": "paper", "url": "https://doi.org/10.1111/j.1600-0889.1983.tb00021.x"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Source and purity not given."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Samples from 48&deg; N to 65&deg; S in the Atlantic in late 1981."}], "method": "The multiple equilibrium technique was used to measure the Henry's law constant as described elsewhere [1]. A known volume of seawater in a syringe was shaken with a known volume of trichloromethane. After equilibration, the headspace was separated and analyzed for trichloromethane. A gas chromatograph fitted with an electron capture detector was used for the analysis.", "reference": {"citation": "McAuliffe, C. D.; Chem. Techn. 1971, 1, 46.", "pubtype": "paper"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.0e+01", "significand": "1.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.500e-01", "significand": "6.500", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "9.864e-04", "significand": "9.864", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "1.046e-01", "significand": "1.046", "exponent": "-1", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.470e-01", "significand": "6.470", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "9.818e-04", "significand": "9.818", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "1.309e-01", "significand": "1.309", "exponent": "-1", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.428e-01", "significand": "6.428", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "9.753e-04", "significand": "9.753", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "1.624e-01", "significand": "1.624", "exponent": "-1", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.377e-01", "significand": "6.377", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "9.675e-04", "significand": "9.675", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Henry's Law Solubility Coefficient", "number": "2.001e-01", "significand": "2.001", "exponent": "-1", "sigfigs": "4", "unit": "m<sup>3</sup> atm mol<sup>-1</sup>"}]}]}]}}