{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/2414/jsonld#"}], "@id": "", "generatedAt": "08-17-26 09:31:15", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/2414/jsonld#", "@type": "sdo:scidataFramework", "uid": "60_225", "title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Rubidium chloride and Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Ari L. Horvath", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["afq:AFQ_0000168", "afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:DEG_C", "sdo:numericvalue", "sdo:stringvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float", "xsd:str"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "Trichloromethane was introduced from a microburet into an aqueous solution of rubidium chloride which contained octanoic acid as indicator. The mixture was vigorously stirred. The pH of the solution at first remained constant right up to the appearance of a second phase, i. e., up to the saturation of the aqueous phase with trichloromethane, after which the pH began to rise. The solubility was calculated from the volume of the aqueous phase and the volume of trichloromethane used for the saturation.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Rubidium chloride", "formula": "RbCl", "casrn": "7791-11-9", "iupacname": "rubidium(1+) chloride", "inchikey": "FGDZQCVHDSGLHJ-UHFFFAOYSA-M"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Trichloromethane", "formula": "CHCl3", "casrn": "67-66-3", "iupacname": "chloroform", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Trichloromethane", "description": "Source and purity not given.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Rubidium chloride", "description": "Source and purity not given.", "substance#": "substance/2/"}, {"@id": "chemical/3/", "@type": "sdo:chemical", "name": "Water", "description": "Distilled (compiler).", "substance#": "substance/3/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Trichloromethane with Rubidium chloride and Water", "type": "ternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.0e+01", "significand": 2.0, "exponent": 1, "sigfigs": 2}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "60:225:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5e-01", "significand": 5.0, "exponent": -1, "sigfigs": 1}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/1/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "60:225:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.85e+01", "significand": 5.85, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.0e+00", "significand": 1.0, "exponent": 0, "sigfigs": 2}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.454e-01", "significand": 6.454, "exponent": -1, "sigfigs": 4}}, {"@id": "datapoint/2/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.0920e-03", "significand": 1.092, "exponent": -3, "sigfigs": 5}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "60:225:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.5e+00", "significand": 1.5, "exponent": 0, "sigfigs": 2}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/3/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "60:225:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.60e+01", "significand": 4.6, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.0e+00", "significand": 2.0, "exponent": 0, "sigfigs": 2}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.738e-01", "significand": 4.738, "exponent": -1, "sigfigs": 4}}, {"@id": "datapoint/4/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.049e-04", "significand": 9.049, "exponent": -4, "sigfigs": 4}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "60:225:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.35e+01", "significand": 4.35, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.5e+00", "significand": 2.5, "exponent": 0, "sigfigs": 2}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.635e-01", "significand": 4.635, "exponent": -1, "sigfigs": 4}}, {"@id": "datapoint/5/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.751e-04", "significand": 8.751, "exponent": -4, "sigfigs": 4}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "60:225:001:001:006", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.97e+01", "significand": 3.97, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Amount concentration (2)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.0e+00", "significand": 3.0, "exponent": 0, "sigfigs": 2}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.852e-01", "significand": 3.852, "exponent": -1, "sigfigs": 4}}, {"@id": "datapoint/6/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/6/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.449e-04", "significand": 8.449, "exponent": -4, "sigfigs": 4}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Pavlovskaya, E. M.; Charykov, A. K.; Tikhomirov, V. I.; J. Gen. Chem. USSR, 1977, 47, 2230-4."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Rubidium chloride and Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-60.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}