{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Orlandini, M.; Fermeglia, M.; Kikic, I.; Alessi, P.; Chem. Eng. J. 1983, 26, 245-50.", "pubtype": "paper", "url": "https://doi.org/10.1016/0300-9467(83)80020-3"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Fluka reagent, further purified by distillation before use."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled (compiler)."}], "method": "A mixture of water and trichloromethane was agitated overnight and left at equilibrium for 24 hours. Three samples were withdrawn from each phase using a syringe and analyzed using gas chromatography. The gas chromatograph (C. Erba ATc/t) was equipped with a Shimadzu Chromatopac E-1A integrator. The stainless column was packed with 100 - 200 mesh Chromosorb W DMCD coated with heptadecane nitrile.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.23e-03", "significand": "1.23", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "5.17e-03", "significand": "5.17", "exponent": "-3", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "8.09e-01", "significand": "8.09", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Percent mass fraction (2)", "number": "7.84e-02", "significand": "7.84", "exponent": "-2", "sigfigs": "3", "unit": "1"}]}]}]}}