{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.", "pubtype": "paper", "url": "https://doi.org/10.1021/je00026a010"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Source and purity not given."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled."}], "method": "A 5 \u00b5L trichloromethane sample was injected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The trichloromethane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.9e+00", "significand": "1.9", "exponent": "0", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "8.251e-01", "significand": "8.251", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.254e-03", "significand": "1.254", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "6.89e+01", "significand": "6.89", "exponent": "1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "1.35e+01", "significand": "1.35", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "7.846e-01", "significand": "7.846", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.192e-03", "significand": "1.192", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.287e+02", "significand": "1.287", "exponent": "2", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "1.57e+01", "significand": "1.57", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "7.565e-01", "significand": "7.565", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.149e-03", "significand": "1.149", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.467e+02", "significand": "1.467", "exponent": "2", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "1.71e+01", "significand": "1.71", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "7.676e-01", "significand": "7.676", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.166e-03", "significand": "1.166", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.550e+02", "significand": "1.550", "exponent": "2", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "2.20e+01", "significand": "2.20", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "7.669e-01", "significand": "7.669", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.165e-03", "significand": "1.165", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.945e+02", "significand": "1.945", "exponent": "2", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "2.49e+01", "significand": "2.49", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "8.297e-01", "significand": "8.297", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.261e-03", "significand": "1.261", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "2.048e+02", "significand": "2.048", "exponent": "2", "sigfigs": "4", "unit": "1"}]}]}]}}