{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Masterton, W. L.; Gendrano, M. C.; J. Phys. Chem. 1966, 70, 2895-8.", "pubtype": "paper", "url": "https://doi.org/10.1021/j100881a029"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Distilled."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source not given. Reagent grade, washed with distilled water and the purity was checked with GC."}], "method": "Trichloromethane was equilibrated with water in an apparatus described elsewhere [1]. The equilibration was allowed to take place for two days with the entire apparatus immersed in a water bath. The organic phase was analyzed for water by the Karl Fischer method (dead-stop end point). The microburet used for the titration was read to \u00b1 0.01 mL. All titrations were carried out in an atmosphere of dry nitrogen.", "reference": {"citation": "Christian, S.; Affsprung, H.; Johanson, J.; J. Chem. Soc. 1963, 1896.", "pubtype": "paper", "url": "https://doi.org/10.1039/jr9630001896"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Amount concentration (1)", "number": "7.38e+01", "significand": "7.38", "exponent": "1", "sigfigs": "3", "unit": "mol/m3"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "8.98e-02", "significand": "8.98", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.92e-03", "significand": "5.92", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}]}]}}