{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Karger, B. L.; Chatterjee, A. K.; King, J. W.; Tech. Rept. No. 3, Dept. of Chemistry, Northeastern Univ.; Boston, Mass.; May 10, 1971.", "pubtype": "report"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "J. T. Baker Chemical Co., reagent grade."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled (compiler)."}], "method": "Gas-liquid chromatography was used for the determination of the partition of trichloromethane with thin layers of water coated on Porasil D. Helium carrier gas was pre-saturated with water at the column temperature. The eluents were detected with an F. & M. flame ionization detector. The partition coefficient ($K_{\\rm{L}}$) was calculated from the slope of the straight line plot of $V_{\\rm{N}}/A_{\\rm{L}}$ versus $V_{\\rm{L}}/A_{\\rm{L}}$.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.25e+01", "significand": "1.25", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.02e+00", "significand": "1.02", "exponent": "0", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.55e-03", "significand": "1.55", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.38e+01", "significand": "1.38", "exponent": "1", "sigfigs": "3", "unit": "1"}]}]}]}}