{"compilation": {"title": "Solubility data from IUPAC SDS Volume 67 (page 458) - Trichloroethene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Prosyanov, N. N.; Shalygin, V. A.; Zel'venskii, Ya. D.; Tr. Mosk. Khim. Tekhnol. Inst. 1973, 100.", "pubtype": "paper"}], "system": "Trichloroethene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled (compiler)."}, {"constituent": 1, "name": "Trichloroethylene", "formula": "C2HCl3", "molweight": 131.388, "casrn": "79-01-6", "inchi": "InChI=1S/C2HCl3/c3-1-2(4)5/h1H", "inchikey": "XSTXAVWGXDQKEL-UHFFFAOYSA-N", "sample": "Source and purity not given."}], "method": "The distribution coefficient was determined by distillation. An inert carrier gas stream was used to take samples from the equilibrium vapor phase. The concentration of the trichloroethene in both liquid and vapor phases was determined by using $\\ce{^{36}Cl}$ labeled compound.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.4e+01", "significand": "1.4", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "3.469e-03", "significand": "3.469", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.757e-02", "significand": "4.757", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.196e+04", "significand": "1.196", "exponent": "4", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.1e+01", "significand": "2.1", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.217e-03", "significand": "6.217", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "8.525e-02", "significand": "8.525", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "9.42e+03", "significand": "9.42", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.2e+01", "significand": "3.2", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.440e-02", "significand": "1.440", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.974e-03", "significand": "1.974", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "6.75e+03", "significand": "6.75", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "5.0e+01", "significand": "5.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "4.696e-02", "significand": "4.696", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "6.442e-03", "significand": "6.442", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "4.36e+03", "significand": "4.36", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "6.0e+01", "significand": "6.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.74e-02", "significand": "9.74", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.334e-04", "significand": "1.334", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "3.06e+03", "significand": "3.06", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "7.03e+01", "significand": "7.03", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "2.06e-01", "significand": "2.06", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "2.836e-04", "significand": "2.836", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "2.07e+03", "significand": "2.07", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "8.0e+01", "significand": "8.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "4.05e-01", "significand": "4.05", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.571e-04", "significand": "5.571", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.45e+03", "significand": "1.45", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "9.03e+01", "significand": "9.03", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "7.12e-01", "significand": "7.12", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "9.825e-04", "significand": "9.825", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.13e+03", "significand": "1.13", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 9, "conditions": [{"property": "Ambient temperature", "number": "9.66e+01", "significand": "9.66", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "8.95e-01", "significand": "8.95", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.237e-05", "significand": "1.237", "exponent": "-5", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "1.08e+03", "significand": "1.08", "exponent": "3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 10, "conditions": [{"property": "Ambient temperature", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.085e+00", "significand": "1.085", "exponent": "0", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.502e-05", "significand": "1.502", "exponent": "-5", "sigfigs": "4", "unit": "1"}, {"property": "Distribution Coefficient (gas/liquid)", "number": "9.80e+02", "significand": "9.80", "exponent": "2", "sigfigs": "3", "unit": "1"}]}]}]}}