{"compilation": {"title": "Solubility data from IUPAC SDS Volume 67 (page 473) - Water with Pentachloroethane", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Staverman, A. J.; Recl. Trav. Chim. Pays-Bas 1941, 60, 836-41.", "pubtype": "paper", "url": "https://doi.org/10.1002/recl.19410601105"}], "system": "Water with Pentachloroethane", "substances": [{"constituent": 2, "name": "Pentachloroethane", "formula": "C2HCl5", "molweight": 202.294, "casrn": "76-01-7", "inchi": "InChI=1S/C2HCl5/c3-1(4)2(5,6)7/h1H", "inchikey": "BNIXVQGCZULYKV-UHFFFAOYSA-N", "sample": "Source and purity not given."}, {"constituent": 1, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled."}], "method": "Water was shaken with pentachloroethane for about 12 hours in a paraffin liquid bath thermostat. The water content of the organic phase was determined by the Karl Fischer titration method. All measurements were carried out in duplicate. The result is an average of two measurements. A full description of the method used is given in a thesis [1].", "reference": {"citation": "Staverman, A. J.; Ph.D. Dissertation, University of Leiden, Leiden, Belgium, 1938.", "pubtype": "dissertation"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "0e+00", "significand": "0", "exponent": "0", "sigfigs": "0", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "1.62e-04", "significand": "1.62", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "1.82e-03", "significand": "1.82", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "8.99e-06", "significand": "8.99", "exponent": "-6", "sigfigs": "3", "unit": "mol/g"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "3.47e-04", "significand": "3.47", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "3.91e-03", "significand": "3.91", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "1.93e-05", "significand": "1.93", "exponent": "-5", "sigfigs": "3", "unit": "mol/g"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mass fraction (1)", "number": "4.14e-04", "significand": "4.14", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.65e-03", "significand": "4.65", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Mole (1) per 100 gram", "number": "2.30e-05", "significand": "2.30", "exponent": "-5", "sigfigs": "3", "unit": "mol/g"}]}]}]}}