Adam Skrzecz 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 4.19e-01 Mole fraction - Liquid (1) 3 4.19 1 -1 5.53e-01 Mole fraction - Liquid (2) 3 5.53 1 1 -1 1.85e-01 Mass fraction (1) 3 1.85 1 -1 8.08e-01 Mass fraction (2) 3 8.08 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 6.96e-01 Mole fraction - Liquid (1) 3 6.96 1 -1 2.29e-01 Mole fraction - Liquid (2) 3 2.29 1 2 -1 4.65e-01 Mass fraction (1) 3 4.65 1 -1 5.07e-01 Mass fraction (2) 3 5.07 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.65e-01 Mole fraction - Liquid (1) 3 7.65 1 -2 9.2e-02 Mole fraction - Liquid (2) 2 9.2 1 3 -1 6.66e-01 Mass fraction (1) 3 6.66 1 -1 2.64e-01 Mass fraction (2) 3 2.64 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.58e-01 Mole fraction - Liquid (1) 3 7.58 1 -2 6.2e-02 Mole fraction - Liquid (2) 2 6.2 1 4 -1 7.11e-01 Mass fraction (1) 3 7.11 1 -1 1.94e-01 Mass fraction (2) 3 1.94 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.25e-01 Mole fraction - Liquid (1) 3 7.25 1 -2 3.9e-02 Mole fraction - Liquid (2) 2 3.9 1 5 -1 7.35e-01 Mass fraction (1) 3 7.35 1 -1 1.30e-01 Mass fraction (2) 3 1.30 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 6.96e-01 Mole fraction - Liquid (1) 3 6.96 1 -2 2.9e-02 Mole fraction - Liquid (2) 2 2.9 1 6 -1 7.36e-01 Mass fraction (1) 3 7.36 1 -1 1.00e-01 Mass fraction (2) 3 1.00 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 6.11e-01 Mole fraction - Liquid (1) 3 6.11 1 -2 1.3e-02 Mole fraction - Liquid (2) 2 1.3 1 7 -1 7.06e-01 Mass fraction (1) 3 7.06 1 -2 5.0e-02 Mass fraction (2) 2 5.0 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 3.56e-01 Mole fraction - Liquid (1) 3 3.56 1 -3 2e-03 Mole fraction - Liquid (2) 1 2 1 8 -1 4.92e-01 Mass fraction (1) 3 4.92 1 -2 1.0e-02 Mass fraction (2) 2 1.0 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 4.16e-01 Mole fraction - Liquid (1) 3 4.16 1 -1 5.48e-01 Mole fraction - Liquid (2) 3 5.48 1 9 -1 1.85e-01 Mass fraction (1) 3 1.85 1 -1 8.06e-01 Mass fraction (2) 3 8.06 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 6.86e-01 Mole fraction - Liquid (1) 3 6.86 1 -1 2.26e-01 Mole fraction - Liquid (2) 3 2.26 1 10 -1 4.62e-01 Mass fraction (1) 3 4.62 1 -1 5.05e-01 Mass fraction (2) 3 5.05 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 7.49e-01 Mole fraction - Liquid (1) 3 7.49 1 -2 8.9e-02 Mole fraction - Liquid (2) 2 8.9 1 11 -1 6.60e-01 Mass fraction (1) 3 6.60 1 -1 2.60e-01 Mass fraction (2) 3 2.60 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 7.42e-01 Mole fraction - Liquid (1) 3 7.42 1 -2 6.1e-02 Mole fraction - Liquid (2) 2 6.1 1 12 -1 7.03e-01 Mass fraction (1) 3 7.03 1 -1 1.92e-01 Mass fraction (2) 3 1.92 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 7.01e-01 Mole fraction - Liquid (1) 3 7.01 1 -2 3.8e-02 Mole fraction - Liquid (2) 2 3.8 1 13 -1 7.21e-01 Mass fraction (1) 3 7.21 1 -1 1.28e-01 Mass fraction (2) 3 1.28 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 6.80e-01 Mole fraction - Liquid (1) 3 6.80 1 -2 2.8e-02 Mole fraction - Liquid (2) 2 2.8 1 14 -1 7.26e-01 Mass fraction (1) 3 7.26 1 -2 9.9e-02 Mass fraction (2) 2 9.9 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 6.11e-01 Mole fraction - Liquid (1) 3 6.11 1 -2 1.4e-02 Mole fraction - Liquid (2) 2 1.4 1 15 -1 7.03e-01 Mass fraction (1) 3 7.03 1 -2 5.4e-02 Mass fraction (2) 2 5.4 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 3.56e-01 Mole fraction - Liquid (1) 3 3.56 1 -3 3e-03 Mole fraction - Liquid (2) 1 3 1 16 -1 4.91e-01 Mass fraction (1) 3 4.91 1 -2 1.2e-02 Mass fraction (2) 2 1.2 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 2.43e-01 Mole fraction - Liquid (1) 3 2.43 1 -1 7.19e-01 Mole fraction - Liquid (2) 3 7.19 1 17 -2 9.2e-02 Mass fraction (1) 2 9.2 1 -1 9.00e-01 Mass fraction (2) 3 9.00 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 4.12e-01 Mole fraction - Liquid (1) 3 4.12 1 -1 5.44e-01 Mole fraction - Liquid (2) 3 5.44 1 18 -1 1.84e-01 Mass fraction (1) 3 1.84 1 -1 8.05e-01 Mass fraction (2) 3 8.05 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 7.08e-01 Mole fraction - Liquid (1) 3 7.08 1 -1 1.55e-01 Mole fraction - Liquid (2) 3 1.55 1 19 -1 5.45e-01 Mass fraction (1) 3 5.45 1 -1 3.96e-01 Mass fraction (2) 3 3.96 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 7.21e-01 Mole fraction - Liquid (1) 3 7.21 1 -1 1.02e-01 Mole fraction - Liquid (2) 3 1.02 1 20 -1 6.22e-01 Mass fraction (1) 3 6.22 1 -1 2.92e-01 Mass fraction (2) 3 2.92 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 7.10e-01 Mole fraction - Liquid (1) 3 7.10 1 -2 6.5e-02 Mole fraction - Liquid (2) 2 6.5 1 21 -1 6.75e-01 Mass fraction (1) 3 6.75 1 -1 2.05e-01 Mass fraction (2) 3 2.05 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 6.71e-01 Mole fraction - Liquid (1) 3 6.71 1 -2 3.5e-02 Mole fraction - Liquid (2) 2 3.5 1 22 -1 7.05e-01 Mass fraction (1) 3 7.05 1 -1 1.21e-01 Mass fraction (2) 3 1.21 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 5.45e-01 Mole fraction - Liquid (1) 3 5.45 1 -3 9e-03 Mole fraction - Liquid (2) 1 9 1 23 -1 6.60e-01 Mass fraction (1) 3 6.60 1 -2 3.6e-02 Mass fraction (2) 2 3.6 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 4.19e-01 Mole fraction - Liquid (1) 3 4.19 1 -3 2e-03 Mole fraction - Liquid (2) 1 2 1 24 -1 5.56e-01 Mass fraction (1) 3 5.56 1 -3 9e-03 Mass fraction (2) 1 9 1 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -2 3.3e-02 Mass fraction (1) 2 3.3 1 -1 9.65e-01 Mass fraction (2) 3 9.65 1 1 -1 1.01e-01 Mole fraction - Liquid (1) 3 1.01 1 -1 8.88e-01 Mole fraction - Liquid (2) 3 8.88 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.21e-01 Mass fraction (1) 3 7.21 1 -2 5.7e-02 Mass fraction (2) 2 5.7 1 2 -1 6.36e-01 Mole fraction - Liquid (1) 3 6.36 1 -2 1.5e-02 Mole fraction - Liquid (2) 2 1.5 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -2 3.5e-02 Mass fraction (1) 2 3.5 1 -1 9.63e-01 Mass fraction (2) 3 9.63 1 3 -1 1.06e-01 Mole fraction - Liquid (1) 3 1.06 1 -1 8.83e-01 Mole fraction - Liquid (2) 3 8.83 1 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 7.15e-01 Mass fraction (1) 3 7.15 1 -2 6.8e-02 Mass fraction (2) 2 6.8 1 4 -1 6.38e-01 Mole fraction - Liquid (1) 3 6.38 1 -2 1.8e-02 Mole fraction - Liquid (2) 2 1.8 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -2 5.0e-02 Mass fraction (1) 2 5.0 1 -1 9.46e-01 Mass fraction (2) 3 9.46 1 5 -1 1.46e-01 Mole fraction - Liquid (1) 3 1.46 1 -1 8.33e-01 Mole fraction - Liquid (2) 3 8.33 1 1 5.0e+01 Ambient temperature 2 5.0 °C 2 3.232e+02 Ambient temperature 4 3.232 $\pu{K}$ -1 7.02e-01 Mass fraction (1) 3 7.02 1 -2 8.8e-02 Mass fraction (2) 2 8.8 1 6 -1 6.37e-01 Mole fraction - Liquid (1) 3 6.37 1 -2 2.4e-02 Mole fraction - Liquid (2) 2 2.4 1 2 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 9.83e-01 Mass fraction (1) 3 9.83 1 1 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 9.82e-01 Mass fraction (1) 3 9.82 1 2 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 9.77e-01 Mass fraction (1) 3 9.77 1 3 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 9.65e-01 Mass fraction (1) 3 9.65 1 4 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 5.17e-01 Mass fraction (1) 3 5.17 1 5 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 3.53e-01 Mass fraction (1) 3 3.53 1 6 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 2.54e-01 Mass fraction (1) 3 2.54 1 7 1 2.0e+01 Ambient temperature 2 2.0 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 2.22e-01 Mass fraction (1) 3 2.22 1 8 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 9.85e-01 Mass fraction (1) 3 9.85 1 9 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 9.77e-01 Mass fraction (1) 3 9.77 1 10 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 9.70e-01 Mass fraction (1) 3 9.70 1 11 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 9.63e-01 Mass fraction (1) 3 9.63 1 12 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 5.25e-01 Mass fraction (1) 3 5.25 1 13 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 3.51e-01 Mass fraction (1) 3 3.51 1 14 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 2.56e-01 Mass fraction (1) 3 2.56 1 15 1 3.0e+01 Ambient temperature 2 3.0 °C 2 3.032e+02 Ambient temperature 4 3.032 $\pu{K}$ -1 2.17e-01 Mass fraction (1) 3 2.17 1 16 3 Solubility, Solubility data series The titration method was used. Binary mixtures of known volumes were titrated with the third component in glass-stoppered bottles until, after vigorously shaking, the mixture became turbid. The equilibrium phases were determined by titrating with water binary methanol-xylene mixtures. The xylene-rich phase was at the beginning the lower layer, but addition of water caused this phase to separate as the upper layer. To determine tie immersed in a thermostat bath, shaken, and after separation one component of each phase was analyzed by the Karl Fischer reagent and xylene, in the hydrocarbon-rich phase, was determined by extraction with water. The results were presented on a Gibbs triangle together with binodal curve. The International Union of Pure and Applied Chemistry Hartley, J.; J. Soc. Chem. Ind. (London) 69, 60-1 (1950). paper https://doi.org/10.1002/jctb.5000690208 67-56-1 1 CH4O InChI=1S/CH4O/c1-2/h2H,1H3 OKKJLVBELUTLKV-UHFFFAOYSA-N 32.0419 Methanol BDH, sulpher free; distilled; fraction boiling at the range 140-142°C was used. 1330-20-7 2 C8H10 0.0 Xylene (isomer mix) Source not specified; absolute alcohol; used as received. 7732-18-5 3 H2O InChI=1S/H2O/h1H2 XLYOFNOQVPJJNP-UHFFFAOYSA-N 18.0153 Water Distilled Methanol with Xylene (mix) and Water