{"compilation": {"title": "Solubility data from IUPAC SDS Volume 71 (page ?) - Nitromethane with Water-d2", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Rabinovich, I. B.; Fedorov, V. D.; Pashkin, N. R.; Avdeshyak, M. A.; Pimenov, N. Ya.; Dokl. Akad. Nauk. USSR 105, 108-11 (1955).", "pubtype": "paper"}], "system": "Nitromethane with Water-d2", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Source not specified; purity not specified; purified."}, {"constituent": 2, "name": "Water-d2", "formula": "D2O", "molweight": 20.0276, "casrn": "7789-20-0", "inchi": "InChI=1S/H2O/h1H2/i/hD2", "inchikey": "XLYOFNOQVPJJNP-ZSJDYOACSA-N", "sample": "Not specified."}], "method": "The synthetic method (cloud-clear points) of Alekseev was used. This involves observing the temperature at which a measured mass of one liquid becomes visually soluble in a measured mass of the other liquid.", "dataset": [{"series": 1, "title": "Effect of deuteration on solubility of nitromethane in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.00e+01", "significand": "2.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": [{"property": "Ostwald coefficient", "number": "5.5e+00", "significand": "5.5", "exponent": "0", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.60e+01", "significand": "2.60", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.992e+02", "significand": "2.992", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": [{"property": "Ostwald coefficient", "number": "5.5e+00", "significand": "5.5", "exponent": "0", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "4.00e+01", "significand": "4.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.132e+02", "significand": "3.132", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": [{"property": "Ostwald coefficient", "number": "4.1e+00", "significand": "4.1", "exponent": "0", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "6.60e+01", "significand": "6.60", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.392e+02", "significand": "3.392", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": [{"property": "Ostwald coefficient", "number": "4.3e+00", "significand": "4.3", "exponent": "0", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "8.00e+01", "significand": "8.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.532e+02", "significand": "3.532", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": [{"property": "Ostwald coefficient", "number": "5.4e+00", "significand": "5.4", "exponent": "0", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "1.000e+02", "significand": "1.000", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.732e+02", "significand": "3.732", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": [{"property": "Ostwald coefficient", "number": "1.0e+01", "significand": "1.0", "exponent": "1", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "1.030e+02", "significand": "1.030", "exponent": "2", "sigfigs": "4", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.762e+02", "significand": "3.762", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": [{"property": "Ostwald coefficient", "number": "4.3e+01", "significand": "4.3", "exponent": "1", "sigfigs": "2", "unit": "1"}]}]}]}}